000838859 001__ 838859
000838859 005__ 20210129231646.0
000838859 0247_ $$2doi$$a10.1021/acsmacrolett.7b00563
000838859 0247_ $$2WOS$$aWOS:000416500000001
000838859 037__ $$aFZJ-2017-07369
000838859 082__ $$a540
000838859 1001_ $$0P:(DE-HGF)0$$aNiebuur, Bart-Jan$$b0
000838859 245__ $$aPressure-Dependence of Poly( N -isopropylacrylamide) Mesoglobule Formation in Aqueous Solution
000838859 260__ $$aWashington, DC$$bACS$$c2017
000838859 3367_ $$2DRIVER$$aarticle
000838859 3367_ $$2DataCite$$aOutput Types/Journal article
000838859 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1522163439_11610
000838859 3367_ $$2BibTeX$$aARTICLE
000838859 3367_ $$2ORCID$$aJOURNAL_ARTICLE
000838859 3367_ $$00$$2EndNote$$aJournal Article
000838859 520__ $$aAbove their cloud point, aqueous solutions of the thermoresponsive polymer poly(N-isopropylacrylamide) (PNIPAM) form large mesoglobules. We have carried out very small-angle neutron scattering (VSANS with q = 0.21–2.3 × 10–3 Å–1) and Raman spectroscopy experiments on a 3 wt % PNIPAM solution in D2O at atmospheric and elevated pressures (up to 113 MPa). Raman spectroscopy reveals that, at high pressure, the polymer is less dehydrated upon crossing the cloud point. VSANS shows that the mesoglobules are significantly larger and contain more D2O than at atmospheric pressure. We conclude that the size of the mesoglobules and thus their growth process are closely related to the hydration state of PNIPAM.
000838859 536__ $$0G:(DE-HGF)POF3-6215$$a6215 - Soft Matter, Health and Life Sciences (POF3-621)$$cPOF3-621$$fPOF III$$x0
000838859 536__ $$0G:(DE-HGF)POF3-6G4$$a6G4 - Jülich Centre for Neutron Research (JCNS) (POF3-623)$$cPOF3-623$$fPOF III$$x1
000838859 588__ $$aDataset connected to CrossRef
000838859 65027 $$0V:(DE-MLZ)SciArea-110$$2V:(DE-HGF)$$aChemistry$$x0
000838859 65027 $$0V:(DE-MLZ)SciArea-210$$2V:(DE-HGF)$$aSoft Condensed Matter$$x1
000838859 65017 $$0V:(DE-MLZ)GC-1603-2016$$2V:(DE-HGF)$$aChemical Reactions and Advanced Materials$$x0
000838859 693__ $$0EXP:(DE-MLZ)KWS3-20140101$$1EXP:(DE-MLZ)FRMII-20140101$$5EXP:(DE-MLZ)KWS3-20140101$$6EXP:(DE-MLZ)NL3auS-20140101$$aForschungs-Neutronenquelle Heinz Maier-Leibnitz $$eKWS-3: Very small angle scattering diffractometer with focusing mirror$$fNL3auS$$x0
000838859 7001_ $$0P:(DE-HGF)0$$aClaude, Kora-Lee$$b1
000838859 7001_ $$0P:(DE-HGF)0$$aPinzek, Simon$$b2
000838859 7001_ $$0P:(DE-HGF)0$$aCariker, Coleman$$b3
000838859 7001_ $$0P:(DE-HGF)0$$aRaftopoulos, Konstantinos N.$$b4
000838859 7001_ $$0P:(DE-Juel1)130893$$aPipich, Vitaliy$$b5
000838859 7001_ $$0P:(DE-Juel1)130507$$aAppavou, Marie-Sousai$$b6$$ufzj
000838859 7001_ $$00000-0003-0824-8572$$aSchulte, Alfons$$b7$$eCorresponding author
000838859 7001_ $$00000-0002-7098-3458$$aPapadakis, Christine M.$$b8$$eCorresponding author
000838859 773__ $$0PERI:(DE-600)2644375-2$$a10.1021/acsmacrolett.7b00563$$gp. 1180 - 1185$$n11$$p1180 - 1185$$tACS Macro Letters$$v6$$x2161-1653$$y2017
000838859 8564_ $$uhttps://juser.fz-juelich.de/record/838859/files/acsmacrolett.7b00563.pdf$$yRestricted
000838859 8564_ $$uhttps://juser.fz-juelich.de/record/838859/files/acsmacrolett.7b00563.gif?subformat=icon$$xicon$$yRestricted
000838859 8564_ $$uhttps://juser.fz-juelich.de/record/838859/files/acsmacrolett.7b00563.jpg?subformat=icon-1440$$xicon-1440$$yRestricted
000838859 8564_ $$uhttps://juser.fz-juelich.de/record/838859/files/acsmacrolett.7b00563.jpg?subformat=icon-180$$xicon-180$$yRestricted
000838859 8564_ $$uhttps://juser.fz-juelich.de/record/838859/files/acsmacrolett.7b00563.jpg?subformat=icon-640$$xicon-640$$yRestricted
000838859 8564_ $$uhttps://juser.fz-juelich.de/record/838859/files/acsmacrolett.7b00563.pdf?subformat=pdfa$$xpdfa$$yRestricted
000838859 909CO $$ooai:juser.fz-juelich.de:838859$$pVDB$$pVDB:MLZ
000838859 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)130893$$aForschungszentrum Jülich$$b5$$kFZJ
000838859 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)130507$$aForschungszentrum Jülich$$b6$$kFZJ
000838859 9131_ $$0G:(DE-HGF)POF3-621$$1G:(DE-HGF)POF3-620$$2G:(DE-HGF)POF3-600$$3G:(DE-HGF)POF3$$4G:(DE-HGF)POF$$9G:(DE-HGF)POF3-6215$$aDE-HGF$$bForschungsbereich Materie$$lVon Materie zu Materialien und Leben$$vIn-house research on the structure, dynamics and function of matter$$x0
000838859 9131_ $$0G:(DE-HGF)POF3-623$$1G:(DE-HGF)POF3-620$$2G:(DE-HGF)POF3-600$$3G:(DE-HGF)POF3$$4G:(DE-HGF)POF$$9G:(DE-HGF)POF3-6G4$$aDE-HGF$$bForschungsbereich Materie$$lVon Materie zu Materialien und Leben$$vFacility topic: Neutrons for Research on Condensed Matter$$x1
000838859 9141_ $$y2017
000838859 915__ $$0StatID:(DE-HGF)0100$$2StatID$$aJCR$$bACS MACRO LETT : 2015
000838859 915__ $$0StatID:(DE-HGF)0200$$2StatID$$aDBCoverage$$bSCOPUS
000838859 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline
000838859 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bThomson Reuters Master Journal List
000838859 915__ $$0StatID:(DE-HGF)0110$$2StatID$$aWoS$$bScience Citation Index
000838859 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection
000838859 915__ $$0StatID:(DE-HGF)0111$$2StatID$$aWoS$$bScience Citation Index Expanded
000838859 915__ $$0StatID:(DE-HGF)1150$$2StatID$$aDBCoverage$$bCurrent Contents - Physical, Chemical and Earth Sciences
000838859 915__ $$0StatID:(DE-HGF)9905$$2StatID$$aIF >= 5$$bACS MACRO LETT : 2015
000838859 920__ $$lyes
000838859 9201_ $$0I:(DE-Juel1)JCNS-FRM-II-20110218$$kJCNS (München) ; Jülich Centre for Neutron Science JCNS (München) ; JCNS-FRM-II$$lJCNS-FRM-II$$x0
000838859 9201_ $$0I:(DE-Juel1)JCNS-1-20110106$$kNeutronenstreuung ; JCNS-1$$lNeutronenstreuung $$x1
000838859 980__ $$ajournal
000838859 980__ $$aVDB
000838859 980__ $$aI:(DE-Juel1)JCNS-FRM-II-20110218
000838859 980__ $$aI:(DE-Juel1)JCNS-1-20110106
000838859 980__ $$aUNRESTRICTED