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@ARTICLE{Napso:839927,
author = {Napso, Sofia and Rein, Dmitry M. and Khalfin, Rafail and
Cohen, Yachin},
title = {{S}emidilute solution structure of cellulose in an ionic
liquid and its mixture with a polar organic co-solvent
studied by small-angle {X}-ray scattering},
journal = {Journal of polymer science / B},
volume = {55},
number = {11},
issn = {0887-6266},
address = {Bognor Regis [u.a.]},
publisher = {Wiley},
reportid = {FZJ-2017-07505},
pages = {888 - 894},
year = {2017},
abstract = {Structural and thermodynamic properties of cellulose
solutions in the ionic liquid 1-ethyl-3-methylimidazolium
acetate (EMIMAc) and its binary mixtures with N,N-dimethyl
formamide (DMF) are studied by small-angle X-ray scattering
(SAXS). These measurements indicate molecular dissolution of
the cellulose chains without any significant aggregation.
The power–law relationships of the evaluated correlation
length and osmotic modulus to concentration exhibit
exponents of −0.76 and 2.06 for EMIMAc and −0.80 and
2.14 for DMF/EMIMAc solvent mixture, respectively. Thus,
these solvents can be considered to be good solvents for
cellulose},
cin = {JCNS (München) ; Jülich Centre for Neutron Science JCNS
(München) ; JCNS-FRM-II / Neutronenstreuung ; JCNS-1},
ddc = {530},
cid = {I:(DE-Juel1)JCNS-FRM-II-20110218 /
I:(DE-Juel1)JCNS-1-20110106},
pnm = {6G4 - Jülich Centre for Neutron Research (JCNS) (POF3-623)
/ 6G15 - FRM II / MLZ (POF3-6G15)},
pid = {G:(DE-HGF)POF3-6G4 / G:(DE-HGF)POF3-6G15},
experiment = {EXP:(DE-MLZ)KWS2-20140101},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000399773000006},
doi = {10.1002/polb.24337},
url = {https://juser.fz-juelich.de/record/839927},
}