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@ARTICLE{Brox:840032,
author = {Brox, Sebastian and Röser, Stephan and Husch, Tamara and
Hildebrand, Stephan and Fromm, Olga and Korth, Martin and
Winter, Martin and Cekic-Laskovic, Isidora},
title = {{A}lternative {S}ingle-{S}olvent {E}lectrolytes {B}ased on
{C}yanoesters for {S}afer {L}ithium-{I}on {B}atteries},
journal = {ChemSusChem},
volume = {9},
number = {13},
issn = {1864-5631},
address = {Weinheim},
publisher = {Wiley-VCH},
reportid = {FZJ-2017-07598},
pages = {1704 - 1711},
year = {2016},
abstract = {To identify alternative single-solvent-based electrolytes
for application in lithium-ion batteries (LIBs), adequate
computational methods were applied to screen specified
physicochemical and electrochemical properties of new
cyanoester-based compounds. Out of 2747 possible target
compounds, two promising candidates and two structurally
equivalent components were chosen. A constructive selection
process including evaluation of basic physicochemical
properties as well assessing the compatibility towards
graphitic anodes was initiated to identify the most
promising candidates. With addition of a film-forming
additive in a low concentration, the most promising
candidate showed an adequate long-term cycling stability
with LiNi1/3Mn1/3Co1/3O2 [NMC(111)] in a full-cell setup
using graphite as anode material. The main advantages of the
new electrolyte formulation are related to its good thermal
behavior, especially with regard to safety in combination
with satisfying electrochemical performance.},
cin = {IEK-12},
ddc = {540},
cid = {I:(DE-Juel1)IEK-12-20141217},
pnm = {131 - Electrochemical Storage (POF3-131)},
pid = {G:(DE-HGF)POF3-131},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:27239982},
UT = {WOS:000380336800021},
doi = {10.1002/cssc.201600369},
url = {https://juser.fz-juelich.de/record/840032},
}