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| Home > Publications database > Hierarchical Ternary MoO2/MoS2/Heteroatom-Doped Carbon Hybrid Materials for High-Performance Lithium-Ion Storage > print |
| 001 | 840038 | ||
| 005 | 20240712113052.0 | ||
| 024 | 7 | _ | |a 10.1002/celc.201600062 |2 doi |
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| 100 | 1 | _ | |a Liu, Haidong |0 P:(DE-HGF)0 |b 0 |
| 245 | _ | _ | |a Hierarchical Ternary MoO2/MoS2/Heteroatom-Doped Carbon Hybrid Materials for High-Performance Lithium-Ion Storage |
| 260 | _ | _ | |a Weinheim |c 2016 |b Wiley-VCH |
| 336 | 7 | _ | |a article |2 DRIVER |
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| 520 | _ | _ | |a The synthesis and electrochemical lithium-ion storage behavior of hierarchical MoO2/MoS2/heteroatom-doped carbon (MoO2/MoS2/HD-C) ternary hybrid have been studied. This ternary hybrid is composed of ultrafine MoO2 nanowires and single/few-layer MoS2 encapsulated by heteroatom-doped carbon, constituting secondary cauliflower-like microspheres. The synthesis is achieved through the synergistic interplay of a polymer and an ionic liquid as structure-directing agents and carbon sources, using a solvothermal reaction followed by a simple thermal treatment. In this unique architecture, each component synergistically acts with a specific purpose. The HD-C matrix with abundant defects and vacancies provides fast electronic conduction as well as interfacial storage, and buffers the volume changes during charging/discharging processes. The ultrasmall dimensions of both MoO2 nanowires and single/few-layered MoS2 components enable rapid Li+ transport in all directions, which is of great benefit to the reversibility of “conversion” reactions. The hierarchical secondary structures assure the robust stability upon long-term cycling. The ternary hybrid material exhibits enhanced Li+-storage performance as well as reversible capacity, rate capability, and cycling stability. A high reversible specific capacity of 1147 mA h g−1 is delivered at 50 mA g−1 together with excellent cycling stability, and 841 mA h g−1 can be retained after 1000 cycles at 500 mA g−1. |
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| 700 | 1 | _ | |a Li, Jie |0 P:(DE-HGF)0 |b 8 |e Corresponding author |
| 773 | _ | _ | |a 10.1002/celc.201600062 |g Vol. 3, no. 6, p. 922 - 932 |0 PERI:(DE-600)2724978-5 |n 6 |p 922 - 932 |t ChemElectroChem |v 3 |y 2016 |x 2196-0216 |
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