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@ARTICLE{Murmann:840039,
      author       = {Murmann, Patrick and Börner, Markus and Cekic-Laskovic,
                      Isidora and Winter, Martin},
      title        = {{I}nfluence of
                      lithium-cyclo-difluoromethane-1,1-bis(sulfonyl)imide as
                      electrolyte additive on the reversibility of lithium metal
                      batteries},
      journal      = {Journal of applied electrochemistry},
      volume       = {46},
      number       = {3},
      issn         = {1572-8838},
      address      = {Dordrecht [u.a.]},
      publisher    = {Springer Science + Business Media B.V},
      reportid     = {FZJ-2017-07605},
      pages        = {339 - 348},
      year         = {2016},
      abstract     = {Electrolyte solutions containing
                      lithium-cyclo-difluoromethane-1,1-bis(sulfonyl)imide
                      (LiDMSI) as an additive were specifically designed for
                      measurements in lithium plating-stripping model experiments
                      on copper electrodes. LiDMSI was implemented into two
                      different electrolyte solutions. The first electrolyte setup
                      consisted of a 1 M solution of LiTFSI in PC as an
                      electrolyte which is known to show a comparably limited
                      performance for reversible Li deposition. The second setup
                      was comprised 1 M LiAsF6 in 1,3-dioxolane as the base
                      electrolyte which depicts a well-tested performance for
                      lithium deposition–dissolution. The addition of LiDMSI
                      yielded significantly improved results in regard to
                      Coulombic efficiencies and cycling stability in both
                      electrolyte compositions. Furthermore, it negated the
                      formation of high surface area, e.g., dendritic lithium,
                      which depicts the main source for the limited safety of
                      rechargeable lithium metal batteries. In the case of the
                      PC-based electrolyte system, the LiDMSI-containing
                      electrolyte illustrates a slightly lowered over-potential on
                      the copper substrate, while for the dioxolane-based setup
                      the over-potentials were almost completely equal. In order
                      to compare the morphologies of the lithium deposits, SEM
                      images were utilized.},
      cin          = {IEK-12},
      ddc          = {540},
      cid          = {I:(DE-Juel1)IEK-12-20141217},
      pnm          = {131 - Electrochemical Storage (POF3-131)},
      pid          = {G:(DE-HGF)POF3-131},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000371469400008},
      doi          = {10.1007/s10800-016-0924-6},
      url          = {https://juser.fz-juelich.de/record/840039},
}