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000840040 1001_ $$0P:(DE-HGF)0$$aMurmann, Patrick$$b0$$eCorresponding author
000840040 245__ $$aInfluence of the Fluorination Degree of Organophosphates on Flammability and Electrochemical Performance in Lithium Ion Batteries: Studies on Fluorinated Compounds Deriving from Triethyl Phosphate
000840040 260__ $$aPennington, NJ$$bElectrochemical Soc.$$c2016
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000840040 520__ $$aThree symmetric substances originating from triethyl phosphate were specifically synthesized with varying degree of fluorination at the side chain. Different concentrations of each phosphate were evaluated as co-solvent with regard to their flammability and the electrochemical cycling performance. With higher degree of fluorination and a higher amount of the phosphate in the electrolyte, the self-extinguishing time (SET), a value to determine and compare the flammability of electrolytes, could be significantly lowered to yield a non-flammable electrolyte mixture. A specifically designed SET device is introduced, which offers more accurate results due to lowered standard deviations by minimizing random and systematic errors. As the application of phosphates as co-solvents results in a trade-off in cycling performance, a thorough determination in regard to the ionic conductivity, the anodic oxidation stability and the compatibility with anode and cathode material was carried out in half- and full-cells. The manuscript strives to establish a deeper understanding of the influence that the utilization of phosphates as co-solvents entail with special focus on the fluorination degree. It could be shown that the partially fluorinated phosphate offers the best cycling results and therefore the lowest trade-off in performance, while a severe improvement in SET could be achieved compared to the reference electrolyte.
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000840040 7001_ $$0P:(DE-HGF)0$$aMönnighoff, Xaver$$b1
000840040 7001_ $$0P:(DE-Juel1)168328$$avon Aspern, Natascha$$b2$$ufzj
000840040 7001_ $$0P:(DE-HGF)0$$aJanssen, Pia$$b3
000840040 7001_ $$0P:(DE-HGF)0$$aKalinovich, Nataliya$$b4
000840040 7001_ $$0P:(DE-HGF)0$$aShevchuk, Michael$$b5
000840040 7001_ $$0P:(DE-HGF)0$$aKazakova, Olesya$$b6
000840040 7001_ $$0P:(DE-HGF)0$$aRöschenthaler, Gerd-Volker$$b7
000840040 7001_ $$0P:(DE-Juel1)171204$$aCekic-Laskovic, Isidora$$b8$$ufzj
000840040 7001_ $$0P:(DE-Juel1)166130$$aWinter, Martin$$b9$$eCorresponding author$$ufzj
000840040 773__ $$0PERI:(DE-600)2002179-3$$a10.1149/2.1031605jes$$gVol. 163, no. 5, p. A751 - A757$$n5$$pA751 - A757$$tJournal of the Electrochemical Society$$v163$$x1945-7111$$y2016
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