% IMPORTANT: The following is UTF-8 encoded.  This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.

@ARTICLE{Murmann:840040,
      author       = {Murmann, Patrick and Mönnighoff, Xaver and von Aspern,
                      Natascha and Janssen, Pia and Kalinovich, Nataliya and
                      Shevchuk, Michael and Kazakova, Olesya and Röschenthaler,
                      Gerd-Volker and Cekic-Laskovic, Isidora and Winter, Martin},
      title        = {{I}nfluence of the {F}luorination {D}egree of
                      {O}rganophosphates on {F}lammability and {E}lectrochemical
                      {P}erformance in {L}ithium {I}on {B}atteries: {S}tudies on
                      {F}luorinated {C}ompounds {D}eriving from {T}riethyl
                      {P}hosphate},
      journal      = {Journal of the Electrochemical Society},
      volume       = {163},
      number       = {5},
      issn         = {1945-7111},
      address      = {Pennington, NJ},
      publisher    = {Electrochemical Soc.},
      reportid     = {FZJ-2017-07606},
      pages        = {A751 - A757},
      year         = {2016},
      abstract     = {Three symmetric substances originating from triethyl
                      phosphate were specifically synthesized with varying degree
                      of fluorination at the side chain. Different concentrations
                      of each phosphate were evaluated as co-solvent with regard
                      to their flammability and the electrochemical cycling
                      performance. With higher degree of fluorination and a higher
                      amount of the phosphate in the electrolyte, the
                      self-extinguishing time (SET), a value to determine and
                      compare the flammability of electrolytes, could be
                      significantly lowered to yield a non-flammable electrolyte
                      mixture. A specifically designed SET device is introduced,
                      which offers more accurate results due to lowered standard
                      deviations by minimizing random and systematic errors. As
                      the application of phosphates as co-solvents results in a
                      trade-off in cycling performance, a thorough determination
                      in regard to the ionic conductivity, the anodic oxidation
                      stability and the compatibility with anode and cathode
                      material was carried out in half- and full-cells. The
                      manuscript strives to establish a deeper understanding of
                      the influence that the utilization of phosphates as
                      co-solvents entail with special focus on the fluorination
                      degree. It could be shown that the partially fluorinated
                      phosphate offers the best cycling results and therefore the
                      lowest trade-off in performance, while a severe improvement
                      in SET could be achieved compared to the reference
                      electrolyte.},
      cin          = {IEK-12},
      ddc          = {540},
      cid          = {I:(DE-Juel1)IEK-12-20141217},
      pnm          = {131 - Electrochemical Storage (POF3-131)},
      pid          = {G:(DE-HGF)POF3-131},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000370866700023},
      doi          = {10.1149/2.1031605jes},
      url          = {https://juser.fz-juelich.de/record/840040},
}