| 001 | 840040 | ||
| 005 | 20240712113052.0 | ||
| 024 | 7 | _ | |a 10.1149/2.1031605jes |2 doi |
| 024 | 7 | _ | |a 0013-4651 |2 ISSN |
| 024 | 7 | _ | |a 0096-4743 |2 ISSN |
| 024 | 7 | _ | |a 0096-4786 |2 ISSN |
| 024 | 7 | _ | |a 1945-7111 |2 ISSN |
| 024 | 7 | _ | |a WOS:000370866700023 |2 WOS |
| 037 | _ | _ | |a FZJ-2017-07606 |
| 041 | _ | _ | |a English |
| 082 | _ | _ | |a 540 |
| 100 | 1 | _ | |a Murmann, Patrick |0 P:(DE-HGF)0 |b 0 |e Corresponding author |
| 245 | _ | _ | |a Influence of the Fluorination Degree of Organophosphates on Flammability and Electrochemical Performance in Lithium Ion Batteries: Studies on Fluorinated Compounds Deriving from Triethyl Phosphate |
| 260 | _ | _ | |a Pennington, NJ |c 2016 |b Electrochemical Soc. |
| 336 | 7 | _ | |a article |2 DRIVER |
| 336 | 7 | _ | |a Output Types/Journal article |2 DataCite |
| 336 | 7 | _ | |a Journal Article |b journal |m journal |0 PUB:(DE-HGF)16 |s 1511188564_32653 |2 PUB:(DE-HGF) |
| 336 | 7 | _ | |a ARTICLE |2 BibTeX |
| 336 | 7 | _ | |a JOURNAL_ARTICLE |2 ORCID |
| 336 | 7 | _ | |a Journal Article |0 0 |2 EndNote |
| 520 | _ | _ | |a Three symmetric substances originating from triethyl phosphate were specifically synthesized with varying degree of fluorination at the side chain. Different concentrations of each phosphate were evaluated as co-solvent with regard to their flammability and the electrochemical cycling performance. With higher degree of fluorination and a higher amount of the phosphate in the electrolyte, the self-extinguishing time (SET), a value to determine and compare the flammability of electrolytes, could be significantly lowered to yield a non-flammable electrolyte mixture. A specifically designed SET device is introduced, which offers more accurate results due to lowered standard deviations by minimizing random and systematic errors. As the application of phosphates as co-solvents results in a trade-off in cycling performance, a thorough determination in regard to the ionic conductivity, the anodic oxidation stability and the compatibility with anode and cathode material was carried out in half- and full-cells. The manuscript strives to establish a deeper understanding of the influence that the utilization of phosphates as co-solvents entail with special focus on the fluorination degree. It could be shown that the partially fluorinated phosphate offers the best cycling results and therefore the lowest trade-off in performance, while a severe improvement in SET could be achieved compared to the reference electrolyte. |
| 536 | _ | _ | |a 131 - Electrochemical Storage (POF3-131) |0 G:(DE-HGF)POF3-131 |c POF3-131 |f POF III |x 0 |
| 588 | _ | _ | |a Dataset connected to CrossRef |
| 700 | 1 | _ | |a Mönnighoff, Xaver |0 P:(DE-HGF)0 |b 1 |
| 700 | 1 | _ | |a von Aspern, Natascha |0 P:(DE-Juel1)168328 |b 2 |u fzj |
| 700 | 1 | _ | |a Janssen, Pia |0 P:(DE-HGF)0 |b 3 |
| 700 | 1 | _ | |a Kalinovich, Nataliya |0 P:(DE-HGF)0 |b 4 |
| 700 | 1 | _ | |a Shevchuk, Michael |0 P:(DE-HGF)0 |b 5 |
| 700 | 1 | _ | |a Kazakova, Olesya |0 P:(DE-HGF)0 |b 6 |
| 700 | 1 | _ | |a Röschenthaler, Gerd-Volker |0 P:(DE-HGF)0 |b 7 |
| 700 | 1 | _ | |a Cekic-Laskovic, Isidora |0 P:(DE-Juel1)171204 |b 8 |u fzj |
| 700 | 1 | _ | |a Winter, Martin |0 P:(DE-Juel1)166130 |b 9 |e Corresponding author |u fzj |
| 773 | _ | _ | |a 10.1149/2.1031605jes |g Vol. 163, no. 5, p. A751 - A757 |0 PERI:(DE-600)2002179-3 |n 5 |p A751 - A757 |t Journal of the Electrochemical Society |v 163 |y 2016 |x 1945-7111 |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/840040/files/J.%20Electrochem.%20Soc.-2016-Murmann-A751-7.pdf |y Restricted |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/840040/files/J.%20Electrochem.%20Soc.-2016-Murmann-A751-7.gif?subformat=icon |x icon |y Restricted |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/840040/files/J.%20Electrochem.%20Soc.-2016-Murmann-A751-7.jpg?subformat=icon-1440 |x icon-1440 |y Restricted |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/840040/files/J.%20Electrochem.%20Soc.-2016-Murmann-A751-7.jpg?subformat=icon-180 |x icon-180 |y Restricted |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/840040/files/J.%20Electrochem.%20Soc.-2016-Murmann-A751-7.jpg?subformat=icon-640 |x icon-640 |y Restricted |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/840040/files/J.%20Electrochem.%20Soc.-2016-Murmann-A751-7.pdf?subformat=pdfa |x pdfa |y Restricted |
| 909 | C | O | |o oai:juser.fz-juelich.de:840040 |p VDB |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 2 |6 P:(DE-Juel1)168328 |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 8 |6 P:(DE-Juel1)171204 |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 9 |6 P:(DE-Juel1)166130 |
| 913 | 1 | _ | |a DE-HGF |l Speicher und vernetzte Infrastrukturen |1 G:(DE-HGF)POF3-130 |0 G:(DE-HGF)POF3-131 |2 G:(DE-HGF)POF3-100 |v Electrochemical Storage |x 0 |4 G:(DE-HGF)POF |3 G:(DE-HGF)POF3 |b Energie |
| 914 | 1 | _ | |y 2017 |
| 915 | _ | _ | |a JCR |0 StatID:(DE-HGF)0100 |2 StatID |b J ELECTROCHEM SOC : 2015 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0200 |2 StatID |b SCOPUS |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0300 |2 StatID |b Medline |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0199 |2 StatID |b Thomson Reuters Master Journal List |
| 915 | _ | _ | |a WoS |0 StatID:(DE-HGF)0110 |2 StatID |b Science Citation Index |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0150 |2 StatID |b Web of Science Core Collection |
| 915 | _ | _ | |a WoS |0 StatID:(DE-HGF)0111 |2 StatID |b Science Citation Index Expanded |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)1150 |2 StatID |b Current Contents - Physical, Chemical and Earth Sciences |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)1160 |2 StatID |b Current Contents - Engineering, Computing and Technology |
| 915 | _ | _ | |a IF < 5 |0 StatID:(DE-HGF)9900 |2 StatID |
| 920 | 1 | _ | |0 I:(DE-Juel1)IEK-12-20141217 |k IEK-12 |l Helmholtz-Institut Münster Ionenleiter für Energiespeicher |x 0 |
| 980 | _ | _ | |a journal |
| 980 | _ | _ | |a VDB |
| 980 | _ | _ | |a I:(DE-Juel1)IEK-12-20141217 |
| 980 | _ | _ | |a UNRESTRICTED |
| 981 | _ | _ | |a I:(DE-Juel1)IMD-4-20141217 |
| Library | Collection | CLSMajor | CLSMinor | Language | Author |
|---|
Gast ::