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@ARTICLE{Grande:840055,
author = {Grande, Lorenzo and Ochel, Anders and Monaco, Simone and
Mastragostino, Marina and Tonti, Dino and Palomino, Pablo
and Paillard, Elie-Elisée and Passerini, Stefano},
title = {{L}i/air {F}low {B}attery {E}mploying {I}onic {L}iquid
{E}lectrolytes},
journal = {Energy technology},
volume = {4},
number = {1},
issn = {2194-4288},
address = {Weinheim [u.a.]},
publisher = {Wiley-VCH},
reportid = {FZJ-2017-07619},
pages = {85 - 89},
year = {2016},
abstract = {Despite the considerable initial optimism behind its
development and prospective commercialization, the Li/air
battery chemistry has now reached a mature stage of
development, which has served to highlight the main
underlying technological limitations, as well as what can
realistically be expected from it. One of the main
challenges is the control of the discharge product
morphology, that is, Li2O2, onto the positive electrode. In
this article, we show how the three-phase configuration
required to ensure cell operation can be induced in a
two-phase system made of mesoporous carbon and an ionic
liquid electrolyte [N-butyl-N-methylpyrrolidinium
bis(trifluoromethane sulfonyl)imide, Pyr14TFSI] by means of
an oxygen-bubbling device (OBD) and a peristaltic pump. The
use of a non-flammable, non-volatile electrolyte ensures
long-term, extensive discharging (up to
4.78 mAh cm−2), as well as operation at temperatures
higher than room temperature.},
cin = {IEK-12},
ddc = {620},
cid = {I:(DE-Juel1)IEK-12-20141217},
pnm = {131 - Electrochemical Storage (POF3-131)},
pid = {G:(DE-HGF)POF3-131},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000370257300010},
doi = {10.1002/ente.201500247},
url = {https://juser.fz-juelich.de/record/840055},
}