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@ARTICLE{Gottselig:840068,
author = {Gottselig, N. and Amelung, Wulf and Kirchner, J. W. and
Bol, R. and Eugster, W. and Granger, S. J. and
Hernández-Crespo, C. and Herrmann, F. and Keizer, J. J. and
Korkiakoski, M. and Laudon, H. and Lehner, I. and Löfgren,
S. and Lohila, A. and Macleod, C. J. A. and Mölder, M. and
Müller, C. and Nasta, P. and Nischwitz, V. and
Paul-Limoges, E. and Pierret, M. C. and Pilegaard, K. and
Romano, N. and Sebastià, M. T. and Stähli, M. and Voltz,
M. and Vereecken, H. and Siemens, J. and Klumpp, E.},
title = {{E}lemental {C}omposition of {N}atural {N}anoparticles and
{F}ine {C}olloids in {E}uropean {F}orest {S}tream {W}aters
and {T}heir {R}ole as {P}hosphorus {C}arriers},
journal = {Global biogeochemical cycles},
volume = {31},
number = {10},
issn = {0886-6236},
address = {Hoboken, NJ},
publisher = {Wiley},
reportid = {FZJ-2017-07632},
pages = {1592 - 1607},
year = {2017},
abstract = {Biogeochemical cycling of elements largely occurs in
dissolved state, but many elements may also be bound to
natural nanoparticles (NNP, 1–100 nm) and fine colloids
(100–450 nm). We examined the hypothesis that the size and
composition of stream water NNP and colloids vary
systematically across Europe. To test this hypothesis, 96
stream water samples were simultaneously collected in 26
forested headwater catchments along two transects across
Europe. Three size fractions (~1–20 nm, >20–60 nm, and
>60 nm) of NNP and fine colloids were identified with Field
Flow Fractionation coupled to inductively coupled plasma
mass spectrometry and an organic carbon detector. The
results showed that NNP and fine colloids constituted
between 2 ± $5\%$ (Si) and 53 ± $21\%$ (Fe; mean ± SD) of
total element concentrations, indicating a substantial
contribution of particles to element transport in these
European streams, especially for P and Fe. The particulate
contents of Fe, Al, and organic C were correlated to their
total element concentrations, but those of particulate Si,
Mn, P, and Ca were not. The fine colloidal fractions >60 nm
were dominated by clay minerals across all sites. The
resulting element patterns of NNP <60 nm changed from North
to South Europe from Fe- to Ca-dominated particles, along
with associated changes in acidity, forest type, and
dominant lithology.},
cin = {IBG-3},
ddc = {550},
cid = {I:(DE-Juel1)IBG-3-20101118},
pnm = {255 - Terrestrial Systems: From Observation to Prediction
(POF3-255)},
pid = {G:(DE-HGF)POF3-255},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000416625200010},
doi = {10.1002/2017GB005657},
url = {https://juser.fz-juelich.de/record/840068},
}