% IMPORTANT: The following is UTF-8 encoded.  This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.

@ARTICLE{Hao:840125,
      author       = {Hao, Yucheng and Murphy, Gabriel L. and Bosbach, Dirk and
                      Modolo, Giuseppe and Albrecht-Schmitt, Thomas E. and
                      Alekseev, Evgeny},
      title        = {{P}orous {U}ranyl {B}orophosphates with {U}nique
                      {T}hree-{D}imensional {O}pen-{F}ramework {S}tructures},
      journal      = {Inorganic chemistry},
      volume       = {56},
      number       = {15},
      issn         = {1520-510X},
      address      = {Washington, DC},
      publisher    = {American Chemical Society},
      reportid     = {FZJ-2017-07685},
      pages        = {9311 - 9320},
      year         = {2017},
      abstract     = {Two novel alkali-metal uranyl borophosphates have been
                      prepared and characterized for the first time, namely,
                      K5(UO2)2[B2P3O12(OH)]2(OH)(H2O)2 and
                      K2(UO2)12[B(H2PO4)4](PO4)8(OH)(H2O)6 denoted as KUPB1 and
                      KUPB2, respectively. KUPB1 was obtained hydrothermally at
                      220 °C and crystallizes in a monoclinic structure in the
                      chiral space group P21. The unit cell parameters of KUPB1
                      are a = 6.7623(2) Å, b = 19.5584(7) Å, c = 11.0110(4) Å,
                      α = γ = 90°, β = 95.579(3)°, and V = 1449.42(8) Å3. It
                      features a unique three-dimensional (3D) open-framework
                      structure, composed of two corner-sharing linked
                      one-dimensional (1D) anionic borophosphates (BP),
                      [B2P3O13]5–, along the a axis and uranyl phosphate (UP),
                      [(UO2)(PO4)3]7–, chains along the c axis, further bridged
                      by PO4 tetrahedra. Multi-intersectional channels can be
                      observed within the structure, in which the largest 11-ring
                      (11-R) tunnel size is ∼7.0 Å × 8.8 Å. Its simplified
                      framework can be described as a new 4-nodal net topological
                      type with a point symbol of
                      {4.84.10}{42.6}2{43.62.83.102}{82.10}. By modification of
                      the synthetic conditions of KUPB1 through an increase in the
                      amount of H3BO3 as flux 4-fold and a reduction of water as
                      the reaction medium, the novel compound KUPB2 is generated.
                      The unit cell parameters of KUPB2 are a = b = 21.8747(3) Å,
                      c = 7.0652(2) Å, α = β = γ = 90°, and V = 3380.72(12)
                      Å3. KUPB2 crystallizes in a tetragonal structure in the
                      polar space group I4̅2m, and its structure is based on a
                      highly complex 3D framework, {(UO2)12[B(PO4)4](PO4)8}9–,
                      in which 1D 8-R UP [(UO2)(PO4)]− tubes can be observed
                      along the c axis. The [(UO2)(PO4)]− tubes consist of three
                      uranyl chains along the c axis, which are linked alternately
                      by [PO4]3– tetrahedra. Those isolated 1D [(UO2)(PO4)]−
                      tubes are further bridged through [(UO2)4B(PO4)4]−
                      clusters, forming an exceptional 3D open-framework
                      structure. Its simplified cation network is a new 5-nodal
                      net topological type such as
                      {32.43.5.62.7.8}8{34.45.54.62}8{4.62.83}4{42.6}4{44.62}.
                      Their facile hydrothermal synthetic routes, porous structure
                      topology, thermal stability, and Raman spectroscopy
                      properties are reported and discussed.},
      cin          = {IEK-6},
      ddc          = {540},
      cid          = {I:(DE-Juel1)IEK-6-20101013},
      pnm          = {161 - Nuclear Waste Management (POF3-161) / HITEC -
                      Helmholtz Interdisciplinary Doctoral Training in Energy and
                      Climate Research (HITEC) (HITEC-20170406)},
      pid          = {G:(DE-HGF)POF3-161 / G:(DE-Juel1)HITEC-20170406},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:28718634},
      UT           = {WOS:000407405500079},
      doi          = {10.1021/acs.inorgchem.7b01443},
      url          = {https://juser.fz-juelich.de/record/840125},
}