Gast ::
| Hauptseite > Publikationsdatenbank > Porous Uranyl Borophosphates with Unique Three-Dimensional Open-Framework Structures > print |
| Hauptseite > Publikationsdatenbank > Porous Uranyl Borophosphates with Unique Three-Dimensional Open-Framework Structures > print |
| 001 | 840125 | ||
| 005 | 20240712084601.0 | ||
| 024 | 7 | _ | |a 10.1021/acs.inorgchem.7b01443 |2 doi |
| 024 | 7 | _ | |a 0020-1669 |2 ISSN |
| 024 | 7 | _ | |a 1520-510X |2 ISSN |
| 024 | 7 | _ | |a pmid:28718634 |2 pmid |
| 024 | 7 | _ | |a WOS:000407405500079 |2 WOS |
| 024 | 7 | _ | |a altmetric:22143588 |2 altmetric |
| 037 | _ | _ | |a FZJ-2017-07685 |
| 041 | _ | _ | |a English |
| 082 | _ | _ | |a 540 |
| 100 | 1 | _ | |a Hao, Yucheng |0 P:(DE-Juel1)165796 |b 0 |u fzj |
| 245 | _ | _ | |a Porous Uranyl Borophosphates with Unique Three-Dimensional Open-Framework Structures |
| 260 | _ | _ | |a Washington, DC |c 2017 |b American Chemical Society |
| 336 | 7 | _ | |a article |2 DRIVER |
| 336 | 7 | _ | |a Output Types/Journal article |2 DataCite |
| 336 | 7 | _ | |a Journal Article |b journal |m journal |0 PUB:(DE-HGF)16 |s 1511507747_516 |2 PUB:(DE-HGF) |
| 336 | 7 | _ | |a ARTICLE |2 BibTeX |
| 336 | 7 | _ | |a JOURNAL_ARTICLE |2 ORCID |
| 336 | 7 | _ | |a Journal Article |0 0 |2 EndNote |
| 520 | _ | _ | |a Two novel alkali-metal uranyl borophosphates have been prepared and characterized for the first time, namely, K5(UO2)2[B2P3O12(OH)]2(OH)(H2O)2 and K2(UO2)12[B(H2PO4)4](PO4)8(OH)(H2O)6 denoted as KUPB1 and KUPB2, respectively. KUPB1 was obtained hydrothermally at 220 °C and crystallizes in a monoclinic structure in the chiral space group P21. The unit cell parameters of KUPB1 are a = 6.7623(2) Å, b = 19.5584(7) Å, c = 11.0110(4) Å, α = γ = 90°, β = 95.579(3)°, and V = 1449.42(8) Å3. It features a unique three-dimensional (3D) open-framework structure, composed of two corner-sharing linked one-dimensional (1D) anionic borophosphates (BP), [B2P3O13]5–, along the a axis and uranyl phosphate (UP), [(UO2)(PO4)3]7–, chains along the c axis, further bridged by PO4 tetrahedra. Multi-intersectional channels can be observed within the structure, in which the largest 11-ring (11-R) tunnel size is ∼7.0 Å × 8.8 Å. Its simplified framework can be described as a new 4-nodal net topological type with a point symbol of {4.84.10}{42.6}2{43.62.83.102}{82.10}. By modification of the synthetic conditions of KUPB1 through an increase in the amount of H3BO3 as flux 4-fold and a reduction of water as the reaction medium, the novel compound KUPB2 is generated. The unit cell parameters of KUPB2 are a = b = 21.8747(3) Å, c = 7.0652(2) Å, α = β = γ = 90°, and V = 3380.72(12) Å3. KUPB2 crystallizes in a tetragonal structure in the polar space group I4̅2m, and its structure is based on a highly complex 3D framework, {(UO2)12[B(PO4)4](PO4)8}9–, in which 1D 8-R UP [(UO2)(PO4)]− tubes can be observed along the c axis. The [(UO2)(PO4)]− tubes consist of three uranyl chains along the c axis, which are linked alternately by [PO4]3– tetrahedra. Those isolated 1D [(UO2)(PO4)]− tubes are further bridged through [(UO2)4B(PO4)4]− clusters, forming an exceptional 3D open-framework structure. Its simplified cation network is a new 5-nodal net topological type such as {32.43.5.62.7.8}8{34.45.54.62}8{4.62.83}4{42.6}4{44.62}. Their facile hydrothermal synthetic routes, porous structure topology, thermal stability, and Raman spectroscopy properties are reported and discussed. |
| 536 | _ | _ | |a 161 - Nuclear Waste Management (POF3-161) |0 G:(DE-HGF)POF3-161 |c POF3-161 |f POF III |x 0 |
| 536 | _ | _ | |0 G:(DE-Juel1)HITEC-20170406 |x 1 |c HITEC-20170406 |a HITEC - Helmholtz Interdisciplinary Doctoral Training in Energy and Climate Research (HITEC) (HITEC-20170406) |
| 588 | _ | _ | |a Dataset connected to CrossRef |
| 700 | 1 | _ | |a Murphy, Gabriel L. |0 P:(DE-HGF)0 |b 1 |
| 700 | 1 | _ | |a Bosbach, Dirk |0 P:(DE-Juel1)130324 |b 2 |u fzj |
| 700 | 1 | _ | |a Modolo, Giuseppe |0 P:(DE-Juel1)130383 |b 3 |u fzj |
| 700 | 1 | _ | |a Albrecht-Schmitt, Thomas E. |0 P:(DE-HGF)0 |b 4 |
| 700 | 1 | _ | |a Alekseev, Evgeny |0 P:(DE-Juel1)144426 |b 5 |e Corresponding author |u fzj |
| 773 | _ | _ | |a 10.1021/acs.inorgchem.7b01443 |g Vol. 56, no. 15, p. 9311 - 9320 |0 PERI:(DE-600)1484438-2 |n 15 |p 9311 - 9320 |t Inorganic chemistry |v 56 |y 2017 |x 1520-510X |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/840125/files/acs.inorgchem.7b01443.pdf |y Restricted |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/840125/files/acs.inorgchem.7b01443.gif?subformat=icon |x icon |y Restricted |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/840125/files/acs.inorgchem.7b01443.jpg?subformat=icon-1440 |x icon-1440 |y Restricted |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/840125/files/acs.inorgchem.7b01443.jpg?subformat=icon-180 |x icon-180 |y Restricted |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/840125/files/acs.inorgchem.7b01443.jpg?subformat=icon-640 |x icon-640 |y Restricted |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/840125/files/acs.inorgchem.7b01443.pdf?subformat=pdfa |x pdfa |y Restricted |
| 909 | C | O | |o oai:juser.fz-juelich.de:840125 |p VDB |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 0 |6 P:(DE-Juel1)165796 |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 2 |6 P:(DE-Juel1)130324 |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 3 |6 P:(DE-Juel1)130383 |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 5 |6 P:(DE-Juel1)144426 |
| 913 | 1 | _ | |a DE-HGF |l Nukleare Entsorgung und Sicherheit sowie Strahlenforschung |1 G:(DE-HGF)POF3-160 |0 G:(DE-HGF)POF3-161 |2 G:(DE-HGF)POF3-100 |v Nuclear Waste Management |x 0 |4 G:(DE-HGF)POF |3 G:(DE-HGF)POF3 |b Energie |
| 914 | 1 | _ | |y 2017 |
| 915 | _ | _ | |a Nationallizenz |0 StatID:(DE-HGF)0420 |2 StatID |
| 915 | _ | _ | |a JCR |0 StatID:(DE-HGF)0100 |2 StatID |b INORG CHEM : 2015 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0200 |2 StatID |b SCOPUS |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0300 |2 StatID |b Medline |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0310 |2 StatID |b NCBI Molecular Biology Database |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0600 |2 StatID |b Ebsco Academic Search |
| 915 | _ | _ | |a Peer Review |0 StatID:(DE-HGF)0030 |2 StatID |b ASC |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0199 |2 StatID |b Thomson Reuters Master Journal List |
| 915 | _ | _ | |a WoS |0 StatID:(DE-HGF)0110 |2 StatID |b Science Citation Index |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0150 |2 StatID |b Web of Science Core Collection |
| 915 | _ | _ | |a WoS |0 StatID:(DE-HGF)0111 |2 StatID |b Science Citation Index Expanded |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)1150 |2 StatID |b Current Contents - Physical, Chemical and Earth Sciences |
| 915 | _ | _ | |a IF < 5 |0 StatID:(DE-HGF)9900 |2 StatID |
| 920 | 1 | _ | |0 I:(DE-Juel1)IEK-6-20101013 |k IEK-6 |l Nukleare Entsorgung und Reaktorsicherheit |x 0 |
| 980 | _ | _ | |a journal |
| 980 | _ | _ | |a VDB |
| 980 | _ | _ | |a I:(DE-Juel1)IEK-6-20101013 |
| 980 | _ | _ | |a UNRESTRICTED |
| 981 | _ | _ | |a I:(DE-Juel1)IFN-2-20101013 |
| Library | Collection | CLSMajor | CLSMinor | Language | Author |
|---|