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@ARTICLE{MarcosEsteban:840163,
      author       = {Marcos Esteban, Raquel and Schütte, Kai and Marquardt,
                      Dorothea and Barthel, Juri and Beckert, Fabian and
                      Mülhaupt, Rolf and Janiak, Christoph},
      title        = {{S}ynthesis of ruthenium@graphene nanomaterials in
                      propylene carbonate as re-usable catalysts for the
                      solvent-free hydrogenation of benzene},
      journal      = {Nano-structures $\&$ nano-objects},
      volume       = {2},
      issn         = {2352-507X},
      address      = {Amsterdam [u.a.]},
      publisher    = {Elsevier},
      reportid     = {FZJ-2017-07718},
      pages        = {28 - 34},
      year         = {2015},
      note         = {Dedicated to Prof. Ekkehard Hahn on the occasion of his
                      60th birthday},
      abstract     = {Ruthenium nanoparticles (Ru-NPs) can be deposited on
                      thermally reduced graphite oxide (TRGO) in propylene
                      carbonate (PC). Propylene carbonate is a biodegradable and
                      non-toxic solvent. Synthesis of Ru-NPs and deposition on
                      TRGO were achieved by decomposition of ruthenium
                      dodecacarbonyl, Ru3(CO)12, by microwave irradiation.
                      Ru@graphene nanomaterials were identified and characterized
                      by high resolution transmission electron microscopy (TEM,
                      HR-TEM), energy-dispersive X-ray diffraction (EDX), selected
                      area electron diffraction (SAED), X-ray photoelectron
                      spectroscopy (XPS) and powder X-ray diffraction (PXRD) with
                      a small diameter and size distribution of Ru-NPs on TRGO.
                      These Ru@graphene nanomaterials are active catalysts for the
                      solvent-free hydrogenation of benzene to cyclohexane under
                      mild conditions (100 °C, 10 bar) with activities of and
                      over $90\%$ conversion in at least ten consecutive runs.},
      cin          = {ER-C-2},
      ddc          = {530},
      cid          = {I:(DE-Juel1)ER-C-2-20170209},
      pnm          = {143 - Controlling Configuration-Based Phenomena (POF3-143)},
      pid          = {G:(DE-HGF)POF3-143},
      typ          = {PUB:(DE-HGF)16},
      doi          = {10.1016/j.nanoso.2015.07.002},
      url          = {https://juser.fz-juelich.de/record/840163},
}