%0 Journal Article
%A Wegner, Susann
%A Saito, Masaichi
%A Barthel, Juri
%A Janiak, Christoph
%T Soft wet-chemical synthesis of Ru-Sn nanoparticles from single-source ruthenocene-stannole precursors in an ionic liquid
%J Journal of organometallic chemistry
%V 821
%@ 0022-328X
%C New York, NY [u.a.]
%I Elsevier
%M FZJ-2017-07724
%P 192 - 196
%D 2016
%X Microwave-induced decomposition of the single-source precursors of a neutral triple-decker ruthenocene (1) and an anionic ruthenocene (2) both bearing a stannole ligand in the ionic liquid 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIm][BF4]) gives bimetallic ruthenium-tin nanoparticles. Particles of approximate composition Ru2Sn (from 1) and Ru3Sn7 (from 2) were obtained in this soft, wet-chemical synthesis. Transmission electron microscopy (TEM) showed the formation of 2–6 nm particles of Ru2Sn with its average elemental composition determined from energy dispersive X-ray spectroscopy (EDX). Crystalline Ru3Sn7 nanoparticles together with α-Sn nanoparticles of 10–50 nm (from TEM) were elucidated by positive matching of the powder-X-ray diffractogram to the Ru3Sn7 and α-Sn phase and the element composition from EDX.
%F PUB:(DE-HGF)16
%9 Journal Article
%U <Go to ISI:>//WOS:000387633400024
%R 10.1016/j.jorganchem.2016.05.010
%U https://juser.fz-juelich.de/record/840169