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100 | 1 | _ | |a Schmitz, Alexa |0 0000-0002-1075-4194 |b 0 |
245 | _ | _ | |a Synthesis of metal-fluoride nanoparticles supported on thermally reduced graphite oxide |
260 | _ | _ | |a Frankfurt, M. |c 2017 |b Beilstein-Institut zur Förderung der Chemischen Wissenschaften |
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520 | _ | _ | |a Metal-fluoride nanoparticles, (MFx-NPs) with M = Fe, Co, Pr, Eu, supported on different types of thermally reduced graphite oxide (TRGO) were obtained by microwave-assisted thermal decomposition of transition-metal amidinates, (M{MeC[N(iPr)]2}n) or [M(AMD)n] with M = Fe(II), Co(II), Pr(III), and tris(2,2,6,6-tetramethyl-3,5-heptanedionato)europium, Eu(dpm)3, in the presence of TRGO in the ionic liquid (IL) 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIm][BF4]). The crystalline phases of the metal fluorides synthesized in [BMIm][BF4] were identified by powder X-ray diffraction (PXRD) to be MF2 for M = Fe, Co and MF3 for M = Eu, Pr. The diameters and size distributions of MFx@TRGO were from (6 ± 2) to (102 ± 41) nm. Energy-dispersive X-ray spectroscopy (EDX) and X-ray photoelectron spectroscopy (XPS) were used for further characterization of the MFx-NPs. Electrochemical investigations of the FeF2-NPs@TRGO as cathode material for lithium-ion batteries were evaluated by galvanostatic charge/discharge profiles. The results indicate that the FeF2-NPs@TRGO as cathode material can present a specific capacity of 500 mAh/g at a current density of 50 mA/g, including a significant interfacial charge storage contribution. The obtained nanomaterials show a good rate capacity as well (220 mAh/g and 130 mAh/g) at a current density of 200 and 500 mA/g, respectively. |
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700 | 1 | _ | |a Schütte, Kai |0 P:(DE-HGF)0 |b 1 |
700 | 1 | _ | |a Ilievski, Vesko |0 P:(DE-HGF)0 |b 2 |
700 | 1 | _ | |a Barthel, Juri |0 P:(DE-Juel1)130525 |b 3 |
700 | 1 | _ | |a Burk, Laura |0 P:(DE-HGF)0 |b 4 |
700 | 1 | _ | |a Mülhaupt, Rolf |0 P:(DE-HGF)0 |b 5 |
700 | 1 | _ | |a Yue, Junpei |0 P:(DE-HGF)0 |b 6 |
700 | 1 | _ | |a Smarsly, Bernd |0 0000-0001-8452-2663 |b 7 |
700 | 1 | _ | |a Janiak, Christoph |0 0000-0002-6288-9605 |b 8 |e Corresponding author |
773 | _ | _ | |a 10.3762/bjnano.8.247 |g Vol. 8, p. 2474 - 2483 |0 PERI:(DE-600)2583584-1 |p 2474 - 2483 |t Beilstein journal of nanotechnology |v 8 |y 2017 |x 2190-4286 |
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