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@ARTICLE{Smokovych:840451,
      author       = {Smokovych, Iryna and Hasemann, Georg and Krüger, Manja and
                      Scheffler, Michael},
      title        = {{P}olymer {D}erived {O}xidation {B}arrier {C}oatings for
                      {M}o-{S}i-{B} {A}lloys},
      journal      = {Journal of the European Ceramic Society},
      volume       = {37},
      number       = {15},
      issn         = {0955-2219},
      address      = {Amsterdam [u.a.]},
      publisher    = {Elsevier Science},
      reportid     = {FZJ-2017-07967},
      pages        = {4559 - 4565},
      year         = {2017},
      abstract     = {Thermodynamic analysis was carried out to predict the phase
                      composition of a perhydridopolysilazane-type polymer derived
                      ceramic coating on Mo5SiB2 matrix particles after heat
                      treatment. The most probable chemical reactions between
                      these constituents and resulting phases were calculated. The
                      feasibility of PHPS/Mo5SiB2 chemical reactions was proved
                      experimentally. An amorphous SiOxNy phase and free Si were
                      found by X-ray diffraction analysis and Raman spectroscopy.
                      The presence of these two phases explain the improvement in
                      oxidation resistance of the Mo5SiB2 particles, which was
                      found to be as twice as high at 800 °C and 1100 °C in air,
                      compared to the unprotected plain Mo5SiB2 phase. The
                      oxidation of the free silicon provided by the PHPS
                      conversion was addressed as an oxygen trap.},
      cin          = {IEK-2},
      ddc          = {660},
      cid          = {I:(DE-Juel1)IEK-2-20101013},
      pnm          = {111 - Efficient and Flexible Power Plants (POF3-111)},
      pid          = {G:(DE-HGF)POF3-111},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000411296700017},
      doi          = {10.1016/j.jeurceramsoc.2017.06.048},
      url          = {https://juser.fz-juelich.de/record/840451},
}