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@TECHREPORT{Wagner:841225,
author = {Wagner, H. and Horner, H.},
title = {{E}lastic interaction and phase transition in coherent
metal-hydrogen systems},
volume = {1039},
number = {Juel-1039-FF},
address = {Jülich},
publisher = {Kernforschungsanlage Jülich, Verlag},
reportid = {FZJ-2017-08317, Juel-1039-FF},
series = {Berichte der Kernforschungsanlage Jülich},
pages = {95 p.},
year = {1974},
abstract = {We study the statistical mechanics.of hydrogen dissolved in
metals. The underlying model is based on the assumption that
the dominant attractive interaction between the protons in
the metal is of elastic nature. In the f irst part of the
paper we review some general properties of the elastic
interaction. We then discuss theimportance of boundary
conditions for the form of the elastic interaction, which
turns out to be of the Curie-Weiss type with macroscopic
range. In the second part we investigate the $\alpha -
\alpha$' ("gas-liquid") phase transition in the hydrogen
lattice fluid. The long-range part of the elastic
interaction is treated in mean f ieldapproximation. In the
canonical ensemble as opposed to the grand canonical
ensemble one f inds no coexisting phases near the critical
point. Instead there is a continuous transition which
changes into a first-order transition at tricritical points.
In the temperature-density region which normally corresponds
to the two-phase coexistence region the hydrogen density is
inhomogeneous and varies on a macroscopic scale. The
peculiar nature of the a-a' phase transition is due to the
long-range character of the elastic interaction, which
ultimately results from the requirement of coherency of the
host crystal. We argue that coherent metal-hydrogen systems
off er examples of real systems where the classical theory
of phase transitions applies.},
cin = {PRE-2000},
cid = {I:(DE-Juel1)PRE2000-20140101},
pnm = {899 - ohne Topic (POF3-899)},
pid = {G:(DE-HGF)POF3-899},
typ = {PUB:(DE-HGF)3 / PUB:(DE-HGF)29},
url = {https://juser.fz-juelich.de/record/841225},
}