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@INPROCEEDINGS{Jeong:841666,
author = {Jeong, Hyeondeok and Menzler, Norbert H. and Lenser,
Christian and Guillon, Olivier},
title = {{S}olid {O}xide {F}uel {C}ell ({SOFC}) {C}ermet {A}nodes
{R}esistant to {C}arbon {D}eposition and {S}ulfur
{P}oisoning},
reportid = {FZJ-2017-08696},
year = {2017},
abstract = {Due to their high operating temperature (700-1000 ̊C),
solid oxide fuel cells (SOFCs) are in principle able to work
with various types of hydrocarbon fuels, such as natural
gas, reformed coal gas (syngas) and biofuels, without high
cost catalysts or external reformer. Furthermore, SOFCs have
high converting efficiency and environmental compatibility.
Because of these attractive features, SOFCs are expected to
take over a major role in energy converting technologies in
near future. However, for the direct use of commercial hydro
carbon fuels in SOFCs, there are several technical
challenges still remaining such as sulfur poisoning and
carbon deposition on anode surface. Currently,
Ni/yttria-stabilized zirconia (YSZ) cermet is typically used
as an SOFC anode material [1]. Although Ni shows good
catalytic activity for reformation and oxidation of
hydrocarbon fuels, the carbon deposition and sulfur
poisoning on Ni surface remarkably degrades the
electrochemical performance. Therefore, in this study, SOFC
with alternative anode materials to prevent sulfur poisoning
and carbon deposition were manufactured.This work is
financed by the Deutsche Forschungsgemeinschaft (DFG), a
collaborative work of Jülich research center (JÜLICH) and
Technical University of Munich (TUM) and is aiming for the
coupling of a biomass gasification system and an SOFC. The
new cells were manufactured by JÜLICH, and the cells have
been tested at TUM. As an alternative anode,
Ni/gadolinia-doped-ceria (GDC) anode is attempted instead of
Ni/YSZ due to the previous reports due to the better
poisoning resistivity and higher conductivity of GDC than
YSZ [2-3]. The new cell with Ni/GDC alternative anode was
manufactured by tape casting and screen printing according
to procedures established in JÜLICH [4]. The single cell
measurement result of Ni/GDC anode cell shows about 57 $\%$
of current density with 0.7 V than Ni/YSZ anode cell at 800
°C. The reason of low performance was YSZ-GDC mixed phase
formation and different anode microstructure according to
different diffusion velocity between YSZ electrolyte and GDC
in anode. To improve the cell performance, an additional GDC
layer was applied as a diffusion barrier between anode and
electrolyte. The modified cell shows similar anode structure
as standard Ni/YSZ cell with single GDC phase in anode. This
Ni/GDC anode cells will be tested with hydrocarbon fuel at
TUM. The poster summarizes the results obtained so far.},
month = {Jul},
date = {2017-07-26},
organization = {Europe-Korea Conference on Science and
Technology, Kista, Stockholm (Sweden),
26 Jul 2017 - 28 Jul 2017},
subtyp = {After Call},
cin = {IEK-1 / JARA-ENERGY},
cid = {I:(DE-Juel1)IEK-1-20101013 / $I:(DE-82)080011_20140620$},
pnm = {135 - Fuel Cells (POF3-135) / SOFC - Solid Oxide Fuel Cell
(SOFC-20140602) / HITEC - Helmholtz Interdisciplinary
Doctoral Training in Energy and Climate Research (HITEC)
(HITEC-20170406)},
pid = {G:(DE-HGF)POF3-135 / G:(DE-Juel1)SOFC-20140602 /
G:(DE-Juel1)HITEC-20170406},
typ = {PUB:(DE-HGF)24},
url = {https://juser.fz-juelich.de/record/841666},
}