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@INPROCEEDINGS{Jeong:841667,
author = {Jeong, Hyeondeok and Lenser, Christian and Menzler, Norbert
H. and Guillon, Olivier},
title = {{A} {S}tudy of {M}olybdenum-{C}ontaining, {C}eria-{B}ased
{C}eramic {M}aterials for {S}olid {O}xide {F}uel {C}ell
{A}pplication},
reportid = {FZJ-2017-08697},
year = {2018},
abstract = {Ceria based ceramic materials have been widely used as
solid oxide fuel cell (SOFC) components such as diffusion
barriers, electrolytes, and electrode materials. Especially,
in the case of anodes, excellent electro-catalytic activity
is observed due to the mixed ionic and electronic
conduction. This mixed conduction behavior is attributed to
the oxygen-vacancy formation and diffusion associated with
reversible Ce4+/Ce3+ transition. In the same way, the
introduction of elements with multiple oxidation states to
the ceria structure might enhance electronic conductivity,
as well as catalytic activity. Mo6+ ions can be reduced to
lower valence states (e.g Mo5+,4+,3+) which may increase
further electronic conduction. Therefore, Mo-doped ceria was
studied as SOFC anode materials. A series of Ce1-xMoxO2+δ
(CMO) and Ce1-xGd0.1MoxO2+δ (CGMO), (x=0.05, 0.1, and 0.2)
compositions were synthesized by conventional solid-state
reaction and characterized by XRD and DTA-TG. The
synthesized CMO and CGMO were than prepared as paste with
NiO and applied to the cell using a screen printing process.
However, the sintering of CMO and CGMO is limited due to the
poor thermal stability caused by Mo doping. Because of this,
an attempt was made to manufacture the cell using other
processes (gas diffusion and thermal diffusion) and an
electrolyte-supported structure. The presentation summarizes
the study of Mo doped ceria materials from materials
properties to applicability.},
month = {Apr},
date = {2018-04-10},
organization = {93rd DKG Annual Meeting $\&$ Symposium
on High-Performance Ceramics 2018,
München (Germany), 10 Apr 2018 - 13
Apr 2018},
subtyp = {After Call},
cin = {IEK-1 / JARA-ENERGY},
cid = {I:(DE-Juel1)IEK-1-20101013 / $I:(DE-82)080011_20140620$},
pnm = {135 - Fuel Cells (POF3-135) / SOFC - Solid Oxide Fuel Cell
(SOFC-20140602)},
pid = {G:(DE-HGF)POF3-135 / G:(DE-Juel1)SOFC-20140602},
typ = {PUB:(DE-HGF)6},
url = {https://juser.fz-juelich.de/record/841667},
}