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@ARTICLE{Wu:841680,
author = {Wu, Guixuan and Seebold, Sören and Yazhenskikh, Elena and
Hack, Klaus and Müller, Michael},
title = {{V}iscosity {M}odel for {O}xide {M}elts {R}elevant to
{F}uel {S}lags. {P}art 3: {T}he {I}ron {O}xide {C}ontaining
{L}ow {O}rder {S}ystems in the {S}ystem
{S}i{O}2–{A}l2{O}3–{C}a{O}–{M}g{O}–{N}a2{O}–{K}2{O}–{F}e{O}–{F}e2{O}3},
journal = {Fuel processing technology},
volume = {171},
issn = {0378-3820},
address = {New York, NY [u.a.]},
publisher = {Science Direct},
reportid = {FZJ-2018-00003},
pages = {339 - 349},
year = {2018},
abstract = {The viscosity model recently developed for the fully liquid
system SiO2–Al2O3–CaO–MgO–Na2O–K2O is further
extended to describe the viscosity of the iron oxide
containing low order systems in the Newtonian range. The
different structural roles of Fe2 + and Fe3 + to the
viscosity are captured by the associate species. Using the
monomeric associate species in combination with some
specific larger structrual units, the model is capable of
describing the viscosity of the melts FeO, FeO–SiO2,
FeO–Al2O3, Fe2O3–CaO, Fe2O3–MgO, Fe2O3–Na2O, and
Fe2O3–K2O over the whole range of compositions as well as
a wide range of temperatures and oxygen partial pressures
using only one set of model parameters. A new mechanism is
proposed to describe the local viscosity maximum around the
fayalite composition in the FeO–SiO2 melt. The model shows
that the presence of the local viscosity maximum is
dependent on the temperature and oxygen partial pressure.
Moreover, the viscosity maximum caused by Al3 +- or Fe3
+-induced charge compensation is presented and a good
agreement between the calculated viscosities and
experimental data is demonstrated.},
cin = {IEK-2},
ddc = {660},
cid = {I:(DE-Juel1)IEK-2-20101013},
pnm = {111 - Efficient and Flexible Power Plants (POF3-111)},
pid = {G:(DE-HGF)POF3-111},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000425570400037},
doi = {10.1016/j.fuproc.2017.09.002},
url = {https://juser.fz-juelich.de/record/841680},
}