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@ARTICLE{Gao:841934,
author = {Gao, Zhan and Haegel, Franz-Hubert and Huisman, Johan
Alexander and Esser, Odilia and Zimmermann, Egon and
Vereecken, Harry},
title = {{S}pectral induced polarization for the characterisation of
biochar in sand},
journal = {Near surface geophysics},
volume = {15},
number = {6},
issn = {1569-4445},
address = {Houten},
publisher = {EAGE},
reportid = {FZJ-2018-00221},
pages = {645-656},
year = {2017},
abstract = {The use of biochar as a soil amendment attracts increasing
research interest. However, the lack of methods to detect
and monitor biochar in situ limits the validation of the
field-scale application of biochar. Spectral induced
polarization is a potential tool to characterise biochar in
soil. The aim of this study is to investigate the
sensitivity of spectral induced polarization to biochar in
sand and to understand how the physicochemical properties of
both the biochar and the surrounding matrix influence the
spectral induced polarization response. To this end,
spectral induced polarization measurements were conducted on
four types of biochar with different mass fractions
disseminated in saturated sand as a host media with changing
electrical conductivity. In addition, it was investigated
how the spectral induced polarization response depends on
the particle size of biochar. The measured SIP data were
interpreted by Debye decomposition to obtain values for the
peak relaxation time, τpeak; total chargeability, M; and
normalised total chargeability, Mn. Spectral induced
polarization showed a clear and specifically differentiated
response to the presence of all four types of biochars. M
was found to be proportional to the mass fraction of
biochars, although relationships varied for each type of
biochars. τpeak of biochars increased with increasing
particle size. Increased electrolyte concentration enhanced
Mn for all biochars, although again, the specific response
was different for each biochar. In addition, higher
electrolyte concentrations decreased τpeak for biochars
derived from wood through pyrolysis but did not affect
τpeak of biochar derived from miscanthus through
hydrothermal carbonisation. It was concluded that the
spectral induced polarization response of pyrolytic biochars
resembled that of conductors or semiconductors, whereas the
spectral induced polarization response of hydrothermal
carbonisation biochar more closely resembled that of clay.
Overall, the findings in this study suggest that spectral
induced polarization is a promising method for the detection
and characterisation of biochar in soil.},
cin = {IBG-3 / ZEA-2},
ddc = {550},
cid = {I:(DE-Juel1)IBG-3-20101118 / I:(DE-Juel1)ZEA-2-20090406},
pnm = {255 - Terrestrial Systems: From Observation to Prediction
(POF3-255)},
pid = {G:(DE-HGF)POF3-255},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000419112000010},
doi = {10.3997/1873-0604.2017045},
url = {https://juser.fz-juelich.de/record/841934},
}