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@ARTICLE{Yi:842076,
      author       = {Yi, Xiaofeng and Izarova, Natalya V. and Stuckart, Maria
                      and Guérin, David and Thomas, Louis and Lenfant, Stéphane
                      and Vuillaume, Dominique and van Leusen, Jan and Duchon,
                      Tomas and Nemšák, Slavomír and Bourone, Svenja D. M. and
                      Schmitz, Sebastian and Kögerler, Paul},
      title        = {{P}robing {F}rontier {O}rbital {E}nergies of {{C}o 9 ({P} 2
                      {W} 15 ) 3 } {P}olyoxometalate {C}lusters at
                      {M}olecule–{M}etal and {M}olecule–{W}ater {I}nterfaces},
      journal      = {Journal of the American Chemical Society},
      volume       = {139},
      number       = {41},
      issn         = {1520-5126},
      address      = {Washington, DC},
      publisher    = {American Chemical Society},
      reportid     = {FZJ-2018-00357},
      pages        = {14501 - 14510},
      year         = {2017},
      abstract     = {Functionalization of polyoxotungstates with organoarsonate
                      coligands enabling surface decoration was explored for the
                      triangular cluster architectures of the composition
                      [CoII9(H2O)6(OH)3(p-RC6H4AsVO3)2(α-PV2WVI15O56)3]25–
                      ({Co9(P2W15)3}, R = H or NH2), isolated as
                      Na25[Co9(OH)3(H2O)6(C6H5AsO3)2(P2W15O56)3]·86H2O (Na-1;
                      triclinic, P1̅, a = 25.8088(3) Å, b = 25.8336(3) Å, c =
                      27.1598(3) Å, α = 78.1282(11)°, β = 61.7276(14)°, γ =
                      60.6220(14)°, V = 13888.9(3) Å3, Z = 2) and
                      Na25[Co9(OH)3(H2O)6(H2NC6H4AsO3)2(P2W15O56)3]·86H2O (Na-2;
                      triclinic, P1̅, a = 14.2262(2) Å, b = 24.8597(4) Å, c =
                      37.9388(4) Å, α = 81.9672(10)°, β = 87.8161(10)°, γ =
                      76.5409(12)°, V = 12920.6(3) Å3, Z = 2). The axially
                      oriented para-aminophenyl groups in 2 facilitate the
                      formation of self-assembled monolayers on gold surfaces and
                      thus provide a viable molecular platform for charge
                      transport studies of magnetically functionalized
                      polyoxometalates. The title systems were isolated and
                      characterized in the solid state, in aqueous solutions, and
                      on metal surfaces. Using conducting tip atomic force
                      microscopy, the energies of {Co9(P2W15)3} frontier molecular
                      orbitals in the surface-bound state were found to directly
                      correlate with cyclic voltammetry data in aqueous solution.},
      cin          = {PGI-6 / JARA-FIT},
      ddc          = {540},
      cid          = {I:(DE-Juel1)PGI-6-20110106 / $I:(DE-82)080009_20140620$},
      pnm          = {522 - Controlling Spin-Based Phenomena (POF3-522)},
      pid          = {G:(DE-HGF)POF3-522},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:28901755},
      UT           = {WOS:000413503300029},
      doi          = {10.1021/jacs.7b07034},
      url          = {https://juser.fz-juelich.de/record/842076},
}