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@PHDTHESIS{Wei:842212,
author = {Wei, Jianping},
title = {{M}echanical {C}haracterization of {S}olid {O}xide {F}uel
{C}ells and {S}ealants},
volume = {391},
school = {RWTH Aachen},
type = {Dissertation},
address = {Jülich},
publisher = {Forschungszentrum Jülich GmbH Zentralbibliothek, Verlag},
reportid = {FZJ-2018-00468},
isbn = {978-3-95806-266-5},
series = {Schriften des Forschungszentrums Jülich Reihe Energie $\&$
Umwelt / Energy $\&$ Environment},
pages = {II, 151 S.},
year = {2017},
note = {RWTH Aachen, Diss., 2016},
abstract = {Solid oxide fuel cells (SOFCs) have a high application
potential due to the evolved demands in a global energy
network. Characterization of thermo-mechanical aspects, in
particular elastic, fracture and creep behavior of sealants
and anode substrates, is essential to warrant reliable
production and operation of planar SOFCs. In this respect,
several mechanical parameters have been determined and
analyzed to get insight into the mechanical behavior and
possible issues for joining, thermal cycling and long term
reliability of SOFC stacks and systems. For anode
substrates, facture toughness and creep behavior as major
mechanical aspects were studied. In this respect, the room
and elevated temperature fracture toughness of two typical
anode substrate variants (NiO-3YSZ and NiO-8YSZ) were
characterized in oxidized and reduced state, some selected
tests were concluded for a re-oxidized state. Elevated
temperature creep studies concentrated on Ni-8YSZ composites
with different porosities, where different loading
configurations have been compared to assess effects of
compressive and tensile stresses. The interpretation and
analysis of the data were based on analytical and finite
element analysis. Leakage of sealants will lead to a
malfunction of the entire system, hence the structural
integrity of sealants is crucial for a reliable operation of
SOFC stacks and systems. In particular, Ag particle and YSZ
fiber reinforced sealants, based on a glass matrix material
developed in Jülich, were studied in stack operation
relevant as-sintered and annealed state. Sealants supplied
by Ceramics and Glass Institute (CSIC, Madrid, Spain) were
also characterized and compared. Work concentrated on
characterization of fracture stress at elevated temperatures
on specimens mainly in a head-to-head geometry and
complementary torsion tests to investigate the shear
strength. The results of mechanical analysis were supported
by advanced microstructural characterization and
fractography to gain insight into annealing and filler
reinforcement effects.},
cin = {IEK-2},
cid = {I:(DE-Juel1)IEK-2-20101013},
pnm = {899 - ohne Topic (POF3-899)},
pid = {G:(DE-HGF)POF3-899},
typ = {PUB:(DE-HGF)3 / PUB:(DE-HGF)11},
url = {https://juser.fz-juelich.de/record/842212},
}