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@ARTICLE{Marino:842566,
author = {Marino, Emanuele and Kodger, Thomas E. and Crisp, Ryan W.
and Timmerman, Dolf and MacArthur, Katherine E. and Heggen,
Marc and Schall, Peter},
title = {{R}epairing {N}anoparticle {S}urface {D}efects},
journal = {Angewandte Chemie},
volume = {129},
number = {44},
issn = {0044-8249},
address = {Weinheim},
publisher = {Wiley-VCH65543},
reportid = {FZJ-2018-00785},
pages = {13983 - 13987},
year = {2017},
abstract = {Solar devices based on semiconductor nanoparticles require
the use of conductive ligands; however, replacing the
native, insulating ligands with conductive metal
chalcogenide complexes introduces structural defects within
the crystalline nanostructure that act as traps for charge
carriers. We utilized atomically thin semiconductor
nanoplatelets as a convenient platform for studying, both
microscopically and spectroscopically, the development of
defects during ligand exchange with the conductive ligands
Na4SnS4 and (NH4)4Sn2S6. These defects can be repaired via
mild chemical or thermal routes, through the addition of
L-type ligands or wet annealing, respectively. This results
in a higher-quality, conductive, colloidally stable
nanomaterial that may be used as the active film in
optoelectronic devices.},
cin = {ER-C-1 / PGI-5},
ddc = {540},
cid = {I:(DE-Juel1)ER-C-1-20170209 / I:(DE-Juel1)PGI-5-20110106},
pnm = {143 - Controlling Configuration-Based Phenomena (POF3-143)},
pid = {G:(DE-HGF)POF3-143},
typ = {PUB:(DE-HGF)16},
doi = {10.1002/ange.201705685},
url = {https://juser.fz-juelich.de/record/842566},
}