% IMPORTANT: The following is UTF-8 encoded.  This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.

@ARTICLE{Cui:842567,
      author       = {Cui, Chunhua and Heggen, Marc and Zabka, Wolf-Dietrich and
                      Cui, Wei and Osterwalder, Jürg and Probst, Benjamin and
                      Alberto, Roger},
      title        = {{A}tomically dispersed hybrid nickel-iridium sites for
                      photoelectrocatalysis},
      journal      = {Nature Communications},
      volume       = {8},
      number       = {1},
      issn         = {2041-1723},
      address      = {London},
      publisher    = {Nature Publishing Group},
      reportid     = {FZJ-2018-00786},
      pages        = {1341},
      year         = {2017},
      abstract     = {Atomically dispersed supported catalysts can maximize atom
                      efficiency and minimize cost. In spite of much progress in
                      gas-phase catalysis, applying such catalysts in the field of
                      renewable energy coupled with electrochemistry remains a
                      challenge due to their limited durability in electrolyte.
                      Here, we report a robust and atomically dispersed hybrid
                      catalyst formed in situ on a hematite semiconductor support
                      during photoelectrochemical oxygen evolution by
                      electrostatic adsorption of soluble monomeric [Ir(OH)6]2−
                      coupled to positively charged NiOx sites. The alkali-stable
                      [Ir(OH)6]2− features synergistically enhanced activity
                      toward water oxidation through NiOx that acts as a
                      “movable bridge” of charge transfer from the hematite
                      surface to the single iridium center. This hybrid catalyst
                      sustains high performance and stability in alkaline
                      electrolyte for >80 h of operation. Our findings provide a
                      promising path for soluble catalysts that are weakly and
                      reversibly bound to semiconductor-supported
                      hole-accumulation inorganic materials under catalytic
                      reaction conditions as hybrid active sites for
                      photoelectrocatalysis.},
      cin          = {ER-C-1},
      ddc          = {500},
      cid          = {I:(DE-Juel1)ER-C-1-20170209},
      pnm          = {143 - Controlling Configuration-Based Phenomena (POF3-143)},
      pid          = {G:(DE-HGF)POF3-143},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:29116238},
      UT           = {WOS:000414534700005},
      doi          = {10.1038/s41467-017-01545-w},
      url          = {https://juser.fz-juelich.de/record/842567},
}