% IMPORTANT: The following is UTF-8 encoded.  This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.

@ARTICLE{Masliuk:842568,
      author       = {Masliuk, Liudmyla and Heggen, Marc and Noack, Johannes and
                      Girgsdies, Frank and Trunschke, Annette and Hermann, Klaus
                      E. and Willinger, Marc Georg and Schlögl, Robert and
                      Lunkenbein, Thomas},
      title        = {{S}tructural {C}omplexity in {H}eterogeneous {C}atalysis:
                      {C}ataloging {L}ocal {N}anostructures},
      journal      = {The journal of physical chemistry / C},
      volume       = {121},
      number       = {43},
      issn         = {1932-7455},
      address      = {Washington, DC},
      publisher    = {Soc.},
      reportid     = {FZJ-2018-00787},
      pages        = {24093 - 24103},
      year         = {2017},
      abstract     = {We present an analytical route toward a detailed and
                      quantitative description of individual defects in
                      heterogeneous catalysts. The investigation is based on a
                      high resolution scanning transmission electron microscopy
                      (STEM) study using complex (Mo,V)Ox mixed oxide as an
                      example. Tiling the structural regions simplifies the
                      identification of local modifications in the microstructure.
                      Up to 19 different structures were observed that can be
                      listed and classified into different structural motifs,
                      intergrowth, channels, interstitial regions, and
                      inclinations. The observed defects are expressed by the
                      rearrangement of the {(Mo)Mo5O27} building blocks, exhibit
                      different sizes, penetrate the bulk, and can form decoupled
                      surface regions that partially cover the crystallographic
                      bulk. The evaluation of 31 crystals yields an average defect
                      concentration of $3.3\%$ and indicates the absence of
                      identical particles. We have, for example, observed 54 of
                      these rearranged structures close to the surface of one
                      (Mo,V)Ox particle (100 × 50 nm2). A detailed analysis of
                      the atomic arrangement at the surface of this particle
                      suggests a surface composition of (Mo610V230M70)Ox (M = Mo
                      and/or V). The resulting catalog of motifs reproduces
                      individual fragments of the real structure of a catalyst and
                      can reveal detailed defect–activity correlations that will
                      contribute to a better understanding of heterogeneous
                      catalysis.},
      cin          = {ER-C-1},
      ddc          = {540},
      cid          = {I:(DE-Juel1)ER-C-1-20170209},
      pnm          = {143 - Controlling Configuration-Based Phenomena (POF3-143)},
      pid          = {G:(DE-HGF)POF3-143},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000414724300027},
      doi          = {10.1021/acs.jpcc.7b08333},
      url          = {https://juser.fz-juelich.de/record/842568},
}