% IMPORTANT: The following is UTF-8 encoded.  This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.

@ARTICLE{Aviziotis:842570,
      author       = {Aviziotis, Ioannis G. and Duguet, Thomas and Soussi, Khaled
                      and Heggen, Marc and Lafont, Marie-Christine and Morfin,
                      Franck and Mishra, Shashank and Daniele, Stephane and
                      Boudouvis, Andreas G. and Vahlas, Constantin},
      title        = {{C}hemical {V}apor {D}eposition of {A}l 13 {F}e 4 {H}ighly
                      {S}elective {C}atalytic {F}ilms for the
                      {S}emi-{H}ydrogenation of {A}cetylene},
      journal      = {Physica status solidi / A},
      volume       = {215},
      number       = {2},
      issn         = {1862-6300},
      address      = {Weinheim},
      publisher    = {Wiley-VCH},
      reportid     = {FZJ-2018-00789},
      pages        = {1700692 -},
      year         = {2018},
      abstract     = {Catalytic properties of coatings containing the Al13Fe4
                      intermetallic phase are tested in the reaction of
                      semi-hydrogenation of acetylene. The selectivity to ethylene
                      is found as high as $74\%$ close to the reported values for
                      pure, unsupported Al13Fe4. The initial conversion of
                      acetylene to ethylene is $84\%$ and rapidly drops due to the
                      catalytic formation of carbon-based by-products on secondary
                      Al-Fe phases. Coatings are processed through sequential
                      chemical vapor deposition (CVD) of aluminum (5 Torr,
                      180 °C) and iron (40 Torr, 140 °C) layers, followed
                      by in situ annealing for 60 min at 575 °C. Deposition
                      proceeds at high growth rate, resulting in 15 μm thick
                      films. After annealing, coatings are composed of the Al13Fe4
                      phase, co-existing with minor secondary Al-Fe intermetallic
                      phases. Overall, it is shown that films containing complex
                      Al-Fe intermetallic phases can be processed by CVD, opening
                      new routes to the engineering of pure, supported Al13Fe4
                      catalysts on 3D or porous supports.},
      cin          = {ER-C-1},
      ddc          = {530},
      cid          = {I:(DE-Juel1)ER-C-1-20170209},
      pnm          = {143 - Controlling Configuration-Based Phenomena (POF3-143)},
      pid          = {G:(DE-HGF)POF3-143},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000423223700012},
      doi          = {10.1002/pssa.201700692},
      url          = {https://juser.fz-juelich.de/record/842570},
}