TY  - JOUR
AU  - Schmitz-Antoniak, Carolin
AU  - Schmitz, Detlef
AU  - Warland, Anne
AU  - Darbandi, Masih
AU  - Haldar, Soumyajyoti
AU  - Bhandary, Sumanta
AU  - Sanyal, Biplab
AU  - Eriksson, Olle
AU  - Wende, Heiko
TI  - Suppression of the Verwey Transition by Charge Trapping
JO  - Annalen der Physik
VL  - 530
IS  - 3
SN  - 0003-3804
CY  - Berlin
PB  - Wiley-VCH
M1  - FZJ-2018-00792
SP  - 1700363
PY  - 2018
N1  - Online First
AB  - The Verwey transition in Fe3O4 nanoparticles with a mean diameter of 6.3 nm is suppressed after capping the particles with a 3.5 nm thick shell of SiO2. By X‐ray absorption spectroscopy and its associated X‐ray magnetic circular dichroism this suppression can be correlated to localized Fe2+ states and a reduced double exchange visible in different site‐specific magnetization behavior in high magnetic fields. The results are discussed in terms of charge trapping at defects in the Fe3O4/ SiO2 interface and the consequent difficulties in the formation of the common phases of Fe3O4. By comparison to X‐ray absorption spectra of bare Fe3O4 nanoparticles in course of the Verwey transition, particular changes in the spectral shape could be correlated to changes in the number of unoccupied d states for Fe ions at different lattice sites. These findings are supported by density functional theory calculations. 
LB  - PUB:(DE-HGF)16
UR  - <Go to ISI:>//WOS:000428350500010
DO  - DOI:10.1002/andp.201700363
UR  - https://juser.fz-juelich.de/record/842579
ER  -