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@ARTICLE{Hackl:843685,
author = {Hackl, Johanna and Duchon, Tomas and Gottlob, Daniel M. and
Cramm, Stefan and Veltruská, Kateřina and Matolín,
Vladimír and Nemšák, Slavomír and Schneider, Claus M.},
title = {{O}n the growth mechanisms of polar (100) surfaces of ceria
on copper (100)},
journal = {Surface science},
volume = {671},
issn = {0039-6028},
address = {Amsterdam},
publisher = {Elsevier},
reportid = {FZJ-2018-01251},
pages = {1 - 5},
year = {2018},
abstract = {We present a study of temperature dependent growth of
nano-sized ceria islands on a Cu (100) substrate. Low-energy
electron microscopy, micro-electron diffraction, X-ray
absorption spectroscopy, and photoemission electron
microscopy are used to determine the morphology, shape,
chemical state, and crystal structure of the grown islands.
Utilizing real-time observation capabilities, we reveal a
three-way interaction between the ceria, substrate, and
local oxygen chemical potential. The interaction manifests
in the reorientation of terrace boundaries on the Cu (100)
substrate, characteristic of the transition between oxidized
and metallic surface. The reorientation is initiated at
nucleation sites of ceria islands, whose growth direction is
influenced by the proximity of the terrace boundaries. The
grown ceria islands were identified as fully stoichiometric
CeO2 (100) surfaces with a (2 × 2) reconstruction.},
cin = {PGI-6},
ddc = {540},
cid = {I:(DE-Juel1)PGI-6-20110106},
pnm = {522 - Controlling Spin-Based Phenomena (POF3-522)},
pid = {G:(DE-HGF)POF3-522},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000429512100001},
doi = {10.1016/j.susc.2018.01.008},
url = {https://juser.fz-juelich.de/record/843685},
}