000843751 001__ 843751
000843751 005__ 20240711101547.0
000843751 0247_ $$2doi$$a10.1149/2.0991805jes
000843751 0247_ $$2ISSN$$a0013-4651
000843751 0247_ $$2ISSN$$a0096-4743
000843751 0247_ $$2ISSN$$a0096-4786
000843751 0247_ $$2ISSN$$a1945-7111
000843751 0247_ $$2Handle$$a2128/18245
000843751 0247_ $$2WOS$$aWOS:000431803900133
000843751 037__ $$aFZJ-2018-01303
000843751 082__ $$a540
000843751 1001_ $$0P:(DE-Juel1)129946$$aWippermann, Klaus$$b0$$eCorresponding author$$ufzj
000843751 245__ $$aIn Situ Determination of the Water Content of Ionic Liquids
000843751 260__ $$aPennington, NJ$$bElectrochemical Soc.$$c2018
000843751 3367_ $$2DRIVER$$aarticle
000843751 3367_ $$2DataCite$$aOutput Types/Journal article
000843751 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1524550044_25917
000843751 3367_ $$2BibTeX$$aARTICLE
000843751 3367_ $$2ORCID$$aJOURNAL_ARTICLE
000843751 3367_ $$00$$2EndNote$$aJournal Article
000843751 520__ $$aThis study examines the applicability of electrochemical methods to the in situ determination of the water content in proton-conducting ionic liquids (PILs). Two proton-conducting ionic liquids with different acidities and hygroscopicities of the cations, sulfoethylmethylammonium trifluoromethanesulfonate, [2-Sema][TfO] and N,N-diethylmethylammonium trifluoromethanesulfonate, [Dema][TfO], were used. At first, PIL water electrolytes with known water concentrations ([2-Sema][TfO]: 0.64-6.1 wt%, [Dema][TfO]: 0.18-99.5 wt%) were prepared. Then, the influence of the water content on the electrochemical properties, namely the electrical conductivity, charge of hydrogen oxidation, charge of Pt oxide reduction and onset potential of Pt oxidation, were investigated. The four parameters were plotted as a function of the water concentration and fitted by exponential, linear or asymptotic functions. These fits serve as calibration curves that can be used to determine the actual water concentration by measuring one or more of the four parameters investigated. It was found that the measurement of specific ion conductivity is a fast and simple method across a wide range of water concentrations. The evaluation of the Pt oxide reduction charge from cyclic voltammograms is more time-consuming, but provides higher accuracy at low water concentrations, although the accuracy also depends on the nature of the ionic liquid. 
000843751 536__ $$0G:(DE-HGF)POF3-135$$a135 - Fuel Cells (POF3-135)$$cPOF3-135$$fPOF III$$x0
000843751 588__ $$aDataset connected to CrossRef
000843751 7001_ $$0P:(DE-Juel1)129938$$aGiffin, Jürgen$$b1$$ufzj
000843751 7001_ $$0P:(DE-Juel1)140525$$aKorte, Carsten$$b2$$ufzj
000843751 773__ $$0PERI:(DE-600)2002179-3$$a10.1149/2.0991805jes$$gVol. 165, no. 5, p. H263 - H270$$n5$$pH263 - H270$$tJournal of the Electrochemical Society$$v165$$x0013-4651$$y2018
000843751 8564_ $$uhttps://juser.fz-juelich.de/record/843751/files/J.%20Electrochem.%20Soc.-2018-Wippermann-H263-70.pdf$$yOpenAccess
000843751 8564_ $$uhttps://juser.fz-juelich.de/record/843751/files/J.%20Electrochem.%20Soc.-2018-Wippermann-H263-70.gif?subformat=icon$$xicon$$yOpenAccess
000843751 8564_ $$uhttps://juser.fz-juelich.de/record/843751/files/J.%20Electrochem.%20Soc.-2018-Wippermann-H263-70.jpg?subformat=icon-1440$$xicon-1440$$yOpenAccess
000843751 8564_ $$uhttps://juser.fz-juelich.de/record/843751/files/J.%20Electrochem.%20Soc.-2018-Wippermann-H263-70.jpg?subformat=icon-180$$xicon-180$$yOpenAccess
000843751 8564_ $$uhttps://juser.fz-juelich.de/record/843751/files/J.%20Electrochem.%20Soc.-2018-Wippermann-H263-70.jpg?subformat=icon-640$$xicon-640$$yOpenAccess
000843751 8564_ $$uhttps://juser.fz-juelich.de/record/843751/files/J.%20Electrochem.%20Soc.-2018-Wippermann-H263-70.pdf?subformat=pdfa$$xpdfa$$yOpenAccess
000843751 909CO $$ooai:juser.fz-juelich.de:843751$$pdnbdelivery$$pdriver$$pVDB$$popen_access$$popenaire
000843751 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)129946$$aForschungszentrum Jülich$$b0$$kFZJ
000843751 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)129938$$aForschungszentrum Jülich$$b1$$kFZJ
000843751 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)140525$$aForschungszentrum Jülich$$b2$$kFZJ
000843751 9131_ $$0G:(DE-HGF)POF3-135$$1G:(DE-HGF)POF3-130$$2G:(DE-HGF)POF3-100$$3G:(DE-HGF)POF3$$4G:(DE-HGF)POF$$aDE-HGF$$bEnergie$$lSpeicher und vernetzte Infrastrukturen$$vFuel Cells$$x0
000843751 9141_ $$y2018
000843751 915__ $$0StatID:(DE-HGF)0200$$2StatID$$aDBCoverage$$bSCOPUS
000843751 915__ $$0StatID:(DE-HGF)1160$$2StatID$$aDBCoverage$$bCurrent Contents - Engineering, Computing and Technology
000843751 915__ $$0LIC:(DE-HGF)CCBYNCND4$$2HGFVOC$$aCreative Commons Attribution-NonCommercial-NoDerivs CC BY-NC-ND 4.0
000843751 915__ $$0StatID:(DE-HGF)0100$$2StatID$$aJCR$$bJ ELECTROCHEM SOC : 2015
000843751 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection
000843751 915__ $$0StatID:(DE-HGF)0110$$2StatID$$aWoS$$bScience Citation Index
000843751 915__ $$0StatID:(DE-HGF)0111$$2StatID$$aWoS$$bScience Citation Index Expanded
000843751 915__ $$0StatID:(DE-HGF)9900$$2StatID$$aIF < 5
000843751 915__ $$0StatID:(DE-HGF)0510$$2StatID$$aOpenAccess
000843751 915__ $$0StatID:(DE-HGF)1150$$2StatID$$aDBCoverage$$bCurrent Contents - Physical, Chemical and Earth Sciences
000843751 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline
000843751 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bThomson Reuters Master Journal List
000843751 920__ $$lyes
000843751 9201_ $$0I:(DE-Juel1)IEK-3-20101013$$kIEK-3$$lElektrochemische Verfahrenstechnik$$x0
000843751 9801_ $$aFullTexts
000843751 980__ $$ajournal
000843751 980__ $$aVDB
000843751 980__ $$aUNRESTRICTED
000843751 980__ $$aI:(DE-Juel1)IEK-3-20101013
000843751 981__ $$aI:(DE-Juel1)ICE-2-20101013