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@ARTICLE{Schwahn:843894,
      author       = {Schwahn, Dietmar and Pipich, Vitaliy and Kasher, Roni},
      title        = {{P}hase behavior of methacrylic acid, poly(ethylene glycol)
                      methyl ether, and poly(ethylene glycol) methacrylate in
                      aqueous solutions},
      journal      = {Polymer},
      volume       = {121},
      issn         = {0032-3861},
      address      = {Oxford},
      publisher    = {Elsevier Science},
      reportid     = {FZJ-2018-01421},
      pages        = {111 - 123},
      year         = {2017},
      abstract     = {The main issue of this manuscript is the exploration of the
                      solubility of methacrylic acid (MA), and the oligomers of
                      poly(ethylene glycol) methyl ether (MPEG), poly(ethylene
                      glycol) methacrylate (PEGMA), and a mixture of MA and PEGMA.
                      These solutions obey to the class of associating aqueous
                      solutions as hydrogen bonding plays an essential role. All
                      solutions are miscible at ambient temperature. Only a small
                      fraction of the order of 10−5 molecules is involved in a
                      process of aggregation forming about 0.4 μm diameter large
                      colloids whose volume fraction enhances above 70 °C. This
                      increase of aggregation is going hand and hand with phase
                      separation of the solution at temperatures at about 70 °C
                      and above. Spinodal and binodal temperatures of the
                      solutions were determined from thermal composition
                      fluctuations following mean field and renormalized 3D-Ising
                      behavior in dependence of the distance from the spinodal
                      phase boundary.},
      cin          = {JCNS (München) ; Jülich Centre for Neutron Science JCNS
                      (München) ; JCNS-FRM-II / Neutronenstreuung ; JCNS-1},
      ddc          = {540},
      cid          = {I:(DE-Juel1)JCNS-FRM-II-20110218 /
                      I:(DE-Juel1)JCNS-1-20110106},
      pnm          = {6215 - Soft Matter, Health and Life Sciences (POF3-621) /
                      6G15 - FRM II / MLZ (POF3-6G15) / 6G4 - Jülich Centre for
                      Neutron Research (JCNS) (POF3-623)},
      pid          = {G:(DE-HGF)POF3-6215 / G:(DE-HGF)POF3-6G15 /
                      G:(DE-HGF)POF3-6G4},
      experiment   = {EXP:(DE-MLZ)KWS1-20140101 / EXP:(DE-MLZ)KWS3-20140101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000405747100013},
      doi          = {10.1016/j.polymer.2017.06.011},
      url          = {https://juser.fz-juelich.de/record/843894},
}