Hauptseite > Publikationsdatenbank > Phase behavior of methacrylic acid, poly(ethylene glycol) methyl ether, and poly(ethylene glycol) methacrylate in aqueous solutions > print

001     843894
005     20210129232719.0
024 7 _ |a 10.1016/j.polymer.2017.06.011
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024 7 _ |a 0032-3861
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024 7 _ |a 1873-2291
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037 _ _ |a FZJ-2018-01421
041 _ _ |a English
082 _ _ |a 540
100 1 _ |a Schwahn, Dietmar
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245 _ _ |a Phase behavior of methacrylic acid, poly(ethylene glycol) methyl ether, and poly(ethylene glycol) methacrylate in aqueous solutions
260 _ _ |a Oxford
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336 7 _ |a article
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520 _ _ |a The main issue of this manuscript is the exploration of the solubility of methacrylic acid (MA), and the oligomers of poly(ethylene glycol) methyl ether (MPEG), poly(ethylene glycol) methacrylate (PEGMA), and a mixture of MA and PEGMA. These solutions obey to the class of associating aqueous solutions as hydrogen bonding plays an essential role. All solutions are miscible at ambient temperature. Only a small fraction of the order of 10−5 molecules is involved in a process of aggregation forming about 0.4 μm diameter large colloids whose volume fraction enhances above 70 °C. This increase of aggregation is going hand and hand with phase separation of the solution at temperatures at about 70 °C and above. Spinodal and binodal temperatures of the solutions were determined from thermal composition fluctuations following mean field and renormalized 3D-Ising behavior in dependence of the distance from the spinodal phase boundary.
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700 1 _ |a Pipich, Vitaliy
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