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@ARTICLE{Lorson:843898,
      author       = {Lorson, Thomas and Jaksch, Sebastian and Lübtow, Michael
                      M. and Jüngst, Tomasz and Groll, Jürgen and Lühmann,
                      Tessa and Luxenhofer, Robert},
      title        = {{A} {T}hermogelling {S}upramolecular {H}ydrogel with
                      {S}ponge-{L}ike {M}orphology as a {C}ytocompatible {B}ioink},
      journal      = {Biomacromolecules},
      volume       = {18},
      number       = {7},
      issn         = {1526-4602},
      address      = {Columbus, Ohio},
      publisher    = {American Chemical Soc.},
      reportid     = {FZJ-2018-01425},
      pages        = {2161 - 2171},
      year         = {2017},
      abstract     = {Biocompatible polymers that form thermoreversible
                      supramolecular hydrogels have gained great interest in
                      biomaterials research and tissue engineering. When favorable
                      rheological properties are achieved at the same time, they
                      are particularly promising candidates as material that allow
                      for the printing of cells, so-called bioinks. We synthesized
                      a novel thermogelling block copolymer and investigated the
                      rheological properties of its aqueous solution by
                      viscosimetry and rheology. The polymers undergo
                      thermogelation between room temperature and body
                      temperature, form transparent hydrogels of surprisingly high
                      strength (G′ > 1000 Pa) and show rapid and complete shear
                      recovery after stress. Small angle neutron scattering
                      suggests an unusual bicontinuous sponge-like gel network.
                      Excellent cytocompatibility was demonstrated with NIH 3T3
                      fibroblasts, which were incorporated and bioplotted into
                      predefined 3D hydrogel structures without significant loss
                      of viability. The developed materials fulfill all criteria
                      for future use as bioink for biofabrication.},
      cin          = {JCNS (München) ; Jülich Centre for Neutron Science JCNS
                      (München) ; JCNS-FRM-II / Neutronenstreuung ; JCNS-1},
      ddc          = {540},
      cid          = {I:(DE-Juel1)JCNS-FRM-II-20110218 /
                      I:(DE-Juel1)JCNS-1-20110106},
      pnm          = {6G15 - FRM II / MLZ (POF3-6G15) / 6G4 - Jülich Centre for
                      Neutron Research (JCNS) (POF3-623)},
      pid          = {G:(DE-HGF)POF3-6G15 / G:(DE-HGF)POF3-6G4},
      experiment   = {EXP:(DE-MLZ)KWS1-20140101},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:28653854},
      UT           = {WOS:000405444900015},
      doi          = {10.1021/acs.biomac.7b00481},
      url          = {https://juser.fz-juelich.de/record/843898},
}