Hauptseite > Publikationsdatenbank > Honeycomb-lattice antiferromagnet Mn 2 V 2 O 7 : a temperature-dependent x-ray diffraction, neutron diffraction and ESR study > print |
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024 | 7 | _ | |a 10.1088/2053-1591/aa67d6 |2 doi |
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100 | 1 | _ | |a Sun, Y. C. |0 P:(DE-HGF)0 |b 0 |e Corresponding author |
245 | _ | _ | |a Honeycomb-lattice antiferromagnet Mn 2 V 2 O 7 : a temperature-dependent x-ray diffraction, neutron diffraction and ESR study |
260 | _ | _ | |a Bristol |c 2017 |b IOP Publ. |
336 | 7 | _ | |a article |2 DRIVER |
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520 | _ | _ | |a Temperature-dependent x-ray diffraction (XRD), neutron powder diffraction and high-field electron spin resonance (ESR) have been employed to study the structural and magnetic properties of distorted honeycomb lattice Mn2V2O7. The XRD data reveal that upon cooling Mn2V2O7 undergoes a martensitic-like β–α structural phase transition at ~270 K. Upon heating, however, the reversible α–β structural transition takes place at ~210 K, showing the first-order feature of the transition. The temperature range, where the two phases coexist, is well determined. With further decrease in temperature, a paramagnetic-to-antiferromagnetic (AFM) phase transition takes place at T N = ~23 K as indicated by ESR and neutron powder diffraction data. The ESR data demonstrate the AFM resonance modes below T N, which can be well understood by conventional AFM resonance theory with uniaxial anisotropy. |
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