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@ARTICLE{Dhling:844252,
author = {Dähling, Claudia and Houston, Judith E. and Radulescu,
Aurel and Drechsler, Markus and Brugnoni, Monia and Mori,
Hideharu and Pergushov, Dmitry V. and Plamper, Felix A.},
title = {{S}elf-{T}emplated {G}eneration of {T}riggerable and
{R}estorable {N}onequilibrium {M}icelles},
journal = {ACS Macro Letters},
volume = {7},
issn = {2161-1653},
address = {Washington, DC},
publisher = {ACS},
reportid = {FZJ-2018-01693},
pages = {341 - 346},
year = {2018},
abstract = {Conditional variations can lead to micellar transformations
resulting in various (equilibrium) morphologies. However,
creating differently shaped assemblies under the same final
conditions (same ingredients, composition, temperature,
etc.) is challenging. We present a thermoresponsive
polyelectrolyte system allowing a pathway-dependent
preparation of kinetically stable spherical star-like or
cylindrical micelles. In more detail, a temperature-induced
structure switch is used to generate equilibrated
interpolyelectrolyte complex (IPEC) micelles of different
morphologies (templates) below and above the lower critical
solution temperature in the presence of plasticizer (salt).
Then, lowering the salt concentration at a specific
temperature kinetically freezes the formed IPECs, keeping
the respective microstructural information encoded in the
frozen IPEC also at other temperatures. Hence, different
nonequilibrium morphologies at the same final conditions are
provided. The salt-triggered transition from nonequilibrium
to equilibrium micelles can be repeated for the same sample,
highlighting a system with an on-demand changeable and
restorable structure.},
cin = {JCNS (München) ; Jülich Centre for Neutron Science JCNS
(München) ; JCNS-FRM-II / Neutronenstreuung ; JCNS-1},
ddc = {540},
cid = {I:(DE-Juel1)JCNS-FRM-II-20110218 /
I:(DE-Juel1)JCNS-1-20110106},
pnm = {6G15 - FRM II / MLZ (POF3-6G15) / 6G4 - Jülich Centre for
Neutron Research (JCNS) (POF3-623)},
pid = {G:(DE-HGF)POF3-6G15 / G:(DE-HGF)POF3-6G4},
experiment = {EXP:(DE-MLZ)KWS2-20140101},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000428220200013},
doi = {10.1021/acsmacrolett.8b00096},
url = {https://juser.fz-juelich.de/record/844252},
}