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@ARTICLE{Weinrich:844273,
      author       = {Weinrich, Henning and Gehring, Markus and Tempel, Hermann
                      and Kungl, Hans and Eichel, Rüdiger-A.},
      title        = {{I}mpact of the charging conditions on the discharge
                      performance of rechargeable iron-anodes for alkaline
                      iron–air batteries},
      journal      = {Journal of applied electrochemistry},
      volume       = {48},
      issn         = {1572-8838},
      address      = {Dordrecht [u.a.]},
      publisher    = {Springer Science + Business Media B.V},
      reportid     = {FZJ-2018-01714},
      pages        = {451-462},
      year         = {2018},
      abstract     = {Pressed-plate carbonyl iron electrodes for rechargeable
                      iron–air batteries have recently been described to undergo
                      a considerable electrochemical formation before they attain
                      a stable and competitive discharge capacity in concentrated
                      alkaline electrolyte. In this study, the impact of the
                      charging conditions on the discharge performance due to
                      electrochemical formation was investigated. Based on the
                      results, it is demonstrated that the preset charge capacity
                      mainly determines the resulting discharge capacities of the
                      porous electrodes in the steady state at the end of the
                      formation period. Furthermore, the present study elucidates
                      the electrode processes behind formation and expands the
                      existing phenomenological model that has recently been
                      established to explain the evolution of the discharge
                      capacity. Finally, feasible criteria for the comparison of
                      different anode architectures are discussed.},
      cin          = {IEK-9},
      ddc          = {540},
      cid          = {I:(DE-Juel1)IEK-9-20110218},
      pnm          = {131 - Electrochemical Storage (POF3-131) / HITEC -
                      Helmholtz Interdisciplinary Doctoral Training in Energy and
                      Climate Research (HITEC) (HITEC-20170406)},
      pid          = {G:(DE-HGF)POF3-131 / G:(DE-Juel1)HITEC-20170406},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000427492000007},
      doi          = {10.1007/s10800-018-1176-4},
      url          = {https://juser.fz-juelich.de/record/844273},
}