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@ARTICLE{Bhat:844526,
author = {Bhat, Swetha S. M. and Babu, Binson and Feygenson, Mikhail
and Neuefeind, Joerg C. and Shaijumon, M. M.},
title = {{N}anostructured {N}a 2 {T}i 9 {O} 19 for {H}ybrid
{S}odium-{I}on {C}apacitors with {E}xcellent {R}ate
{C}apability},
journal = {ACS applied materials $\&$ interfaces},
volume = {10},
number = {1},
issn = {1944-8252},
address = {Washington, DC},
publisher = {Soc.},
reportid = {FZJ-2018-01936},
pages = {437 - 447},
year = {2018},
abstract = {Herein, we report a new Na-insertion electrode material,
Na2Ti9O19, as a potential candidate for Na-ion hybrid
capacitors. We study the structural properties of
nanostructured Na2Ti9O19, synthesized by a hydrothermal
technique, upon electrochemical cycling vs Na. Average and
local structures of Na2Ti9O19 are elucidated from neutron
Rietveld refinement and pair distribution function (PDF),
respectively, to investigate the initial discharge and
charge events. Rietveld refinement reveals electrochemical
cycling of Na2Ti9O19 is driven by single-phase solid
solution reaction during (de)sodiation without any major
structural deterioration, keeping the average structure
intact. Unit cell volume and lattice evolution on discharge
process is inherently related to TiO6 distortion and Na ion
perturbations, while the PDF reveals the deviation in the
local structure after sodiation. Raman spectroscopy and
X-ray photoelectron spectroscopy studies further corroborate
the average and local structural behavior derived from
neutron diffraction measurements. Also, Na2Ti9O19 shows
excellent Na-ion kinetics with a capacitve nature of $86\%$
at 1.0 mV s–1, indicating that the material is a good
anode candidate for a sodium-ion hybrid capacitor. A full
cell hybrid Na-ion capacitor is fabricated by using
Na2Ti9O19 as anode and activated porous carbon as cathode,
which exhibits excellent electrochemical properties, with a
maximum energy density of 54 Wh kg–1 and a maximum power
density of 5 kW kg–1. Both structural insights and
electrochemical investigation suggest that Na2Ti9O19 is a
promising negative electrode for sodium-ion batteries and
hybrid capacitors.},
cin = {ICS-1 / Neutronenstreuung ; JCNS-1 / JCNS-ESS},
ddc = {540},
cid = {I:(DE-Juel1)ICS-1-20110106 / I:(DE-Juel1)JCNS-1-20110106 /
I:(DE-Juel1)JCNS-ESS-20170404},
pnm = {551 - Functional Macromolecules and Complexes (POF3-551) /
6G4 - Jülich Centre for Neutron Research (JCNS) (POF3-623)
/ 6215 - Soft Matter, Health and Life Sciences (POF3-621)},
pid = {G:(DE-HGF)POF3-551 / G:(DE-HGF)POF3-6G4 /
G:(DE-HGF)POF3-6215},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:29244481},
UT = {WOS:000422814400048},
doi = {10.1021/acsami.7b13300},
url = {https://juser.fz-juelich.de/record/844526},
}