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@ARTICLE{RamrezQuiroz:844547,
author = {Ramírez Quiroz, César Omar and Shen, Yilei and Salvador,
Michael and Forberich, Karen and Schrenker, Nadine and
Spyropoulos, George D. and Heumüller, Thomas and Wilkinson,
Benjamin and Kirchartz, Thomas and Spiecker, Erdmann and
Verlinden, Pierre J. and Zhang, Xueling and Green, Martin A.
and Ho-Baillie, Anita and Brabec, Christoph J.},
title = {{B}alancing electrical and optical losses for efficient
4-terminal {S}i–perovskite solar cells with solution
processed percolation electrode},
journal = {Journal of materials chemistry / A},
volume = {6},
number = {8},
issn = {2050-7496},
address = {London [u.a.]},
publisher = {RSC},
reportid = {FZJ-2018-01954},
pages = {3583 - 3592},
year = {2018},
abstract = {The unprecedented rise in efficiency of perovskite-based
photovoltaics has sparked interest in semi-transparent
devices, particularly for tandem structures. Despite
promising reports regarding efficiency and reduced parasitic
absorption, many devices still rely on processes from the
gas phase, compromising both applicability and cost factors.
Here, we report all-solution perovskite solar cells with
improved infrared transparency ideally suited as top-cells
for efficient multi-junction device configurations. We
demonstrate the functionality of copper(I) thiocyanate as
antireflective layer and as selective contact between the
transparent conductive oxide and the perovskite. This
concept allows us to fabricate an opaque device with steady
state efficiency as high as $20.1\%.$ By employing silver
nanowires with robust environmental stability as the bottom
electrode, we demonstrate different regimes of device
performance that can be described through a classical
percolation model, leading to semi-transparent solar cells
with efficiencies of up to $17.1\%.$ In conjunction with the
implementation of an infrared-tuned transparent conductive
oxide contact deposited on UV-fused silica, we show a full
device average transmittance surpassing $84\%$ between 800
and 1100 nm (as opposed to $77\%$ with PEDOT:PSS as the
selective contact). Finally, we mechanically stacked
optimized perovskite devices on top of high performing PERL
and IBC silicon architectures. The measured imputed output
efficiency of the 4-terminal perovskite–silicon solar cell
was $26.7\%$ and $25.2\%$ for the PERL–perovskite and
IBC–perovskite, respectively.},
cin = {IEK-5 / IEK-11},
ddc = {540},
cid = {I:(DE-Juel1)IEK-5-20101013 / I:(DE-Juel1)IEK-11-20140314},
pnm = {121 - Solar cells of the next generation (POF3-121) / 1213
- Cell Design and Development (POF4-121)},
pid = {G:(DE-HGF)POF3-121 / G:(DE-HGF)POF4-1213},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000425623600032},
doi = {10.1039/C7TA10945H},
url = {https://juser.fz-juelich.de/record/844547},
}