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@ARTICLE{Jones:844625,
author = {Jones, Robert O.},
title = {{B}onding in phase change materials: concepts and
misconceptions},
journal = {Journal of physics / Condensed matter},
volume = {30},
number = {15},
issn = {1361-648X},
address = {Bristol},
publisher = {IOP Publ.},
reportid = {FZJ-2018-02024},
pages = {153001},
year = {2018},
abstract = {Bonding concepts originating in chemistry are surveyed from
a condensed matter perspective, beginning around 1850 with
'valence' and the word 'bond' itself. The analysis of
chemical data in the 19th century resulted in astonishing
progress in understanding the connectivity and
stereochemistry of molecules, almost without input from
physicists until the development of quantum mechanics in
1925 and afterwards. The valence bond method popularized by
Pauling and the molecular orbital methods of Hund, Mulliken,
Bloch, and Hückel play major roles in the subsequent
development, as does the central part played by the kinetic
energy in covalent bonding (Ruedenberg and others).
'Metallic' (free electron) and related approaches, including
pseudopotential and density functional theories, have been
remarkably successful in understanding structures and
bonding in molecules and solids. We discuss these concepts
in the context of phase change materials, which involve the
rapid and reversible transition between amorphous and
crystalline states, and note the confusion that some have
caused, in particular 'resonance' and 'resonant bonding'.},
cin = {IAS-1 / PGI-1 / JARA-FIT / JARA-HPC},
ddc = {530},
cid = {I:(DE-Juel1)IAS-1-20090406 / I:(DE-Juel1)PGI-1-20110106 /
$I:(DE-82)080009_20140620$ / $I:(DE-82)080012_20140620$},
pnm = {142 - Controlling Spin-Based Phenomena (POF3-142) / 143 -
Controlling Configuration-Based Phenomena (POF3-143)},
pid = {G:(DE-HGF)POF3-142 / G:(DE-HGF)POF3-143},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:29480162},
UT = {WOS:000427968800001},
doi = {10.1088/1361-648X/aab22e},
url = {https://juser.fz-juelich.de/record/844625},
}