Hauptseite > Publikationsdatenbank > Charge Transfer Across Oxide Interfaces Probed by in Situ X-ray Photoelectron and Absorption Spectroscopy Techniques > print

001     844946
005     20240711085636.0
024 7 _ |a 10.1021/acs.jpcc.7b10284
|2 doi
024 7 _ |a 1932-7447
|2 ISSN
024 7 _ |a 1932-7455
|2 ISSN
024 7 _ |a WOS:000427331300012
|2 WOS
037 _ _ |a FZJ-2018-02285
082 _ _ |a 540
100 1 _ |a Lenser, Christian
|0 P:(DE-Juel1)138081
|b 0
|e Corresponding author
245 _ _ |a Charge Transfer Across Oxide Interfaces Probed by in Situ X-ray Photoelectron and Absorption Spectroscopy Techniques
260 _ _ |a Washington, DC
|c 2018
|b Soc.
336 7 _ |a article
|2 DRIVER
336 7 _ |a Output Types/Journal article
|2 DataCite
336 7 _ |a Journal Article
|b journal
|m journal
|0 PUB:(DE-HGF)16
|s 1523531462_13025
|2 PUB:(DE-HGF)
336 7 _ |a ARTICLE
|2 BibTeX
336 7 _ |a JOURNAL_ARTICLE
|2 ORCID
336 7 _ |a Journal Article
|0 0
|2 EndNote
520 _ _ |a The interface between two functional oxide materials governs the physical, chemical, and electronic interactions between the two phases. We investigate the charge transfer across the interface between two structurally related material classes, namely, perovskite and Ruddlesden–Popper-type oxides, choosing La0.8Sr0.2CoO3−δ (LSC) and Nd2NiO4+δ (NNO) as our model systems for the two classes, respectively. The interface of Nd2NiO4+δ and La0.8Sr0.2CoO3−δ is investigated using in situ photoemission spectroscopy techniques on epitaxial thin films. A detailed analysis of the electronic structure with X-ray photoelectron spectroscopy and X-ray absorption spectroscopy under an oxygen atmosphere and at elevated temperature reveals charge transfer from La0.8Sr0.2CoO3−δ into Nd2NiO4+δ. Through the use of electrical conductivity relaxation, it is demonstrated that such charge transfer from LSC into NNO is accompanied by a reduction in the kinetics of oxygen exchange on Nd2NiO4+δ, contrary to expectation. Fermi level pinning at the surface of Nd2NiO4+δ is discussed as a possible cause for this phenomenon. These insights add to the understanding of material interaction necessary for the design of next-generation high-performance electrochemical components.
536 _ _ |a 135 - Fuel Cells (POF3-135)
|0 G:(DE-HGF)POF3-135
|c POF3-135
|f POF III
|x 0
588 _ _ |a Dataset connected to CrossRef
700 1 _ |a Lu, Qiyang
|0 0000-0002-9155-3684
|b 1
700 1 _ |a Crumlin, Ethan
|0 0000-0003-3132-190X
|b 2
700 1 _ |a Bluhm, Hendrik
|0 0000-0001-9381-3155
|b 3
700 1 _ |a Yildiz, Bilge
|0 P:(DE-HGF)0
|b 4
|e Corresponding author
773 _ _ |a 10.1021/acs.jpcc.7b10284
|g Vol. 122, no. 9, p. 4841 - 4848
|0 PERI:(DE-600)2256522-X
|n 9
|p 4841 - 4848
|t The @journal of physical chemistry / C
|v 122
|y 2018
|x 1932-7447
856 4 _ |u https://juser.fz-juelich.de/record/844946/files/Charge%20Transfer%20Across%20Oxide%20Interfaces%20Probed%20by%20in%20Situ%20X-ray%20Photoelectron%20and%20Absorption%20Spectroscopy%20Techniques.pdf
|y Restricted
856 4 _ |u https://juser.fz-juelich.de/record/844946/files/Charge%20Transfer%20Across%20Oxide%20Interfaces%20Probed%20by%20in%20Situ%20X-ray%20Photoelectron%20and%20Absorption%20Spectroscopy%20Techniques.gif?subformat=icon
|x icon
|y Restricted
856 4 _ |u https://juser.fz-juelich.de/record/844946/files/Charge%20Transfer%20Across%20Oxide%20Interfaces%20Probed%20by%20in%20Situ%20X-ray%20Photoelectron%20and%20Absorption%20Spectroscopy%20Techniques.jpg?subformat=icon-1440
|x icon-1440
|y Restricted
856 4 _ |u https://juser.fz-juelich.de/record/844946/files/Charge%20Transfer%20Across%20Oxide%20Interfaces%20Probed%20by%20in%20Situ%20X-ray%20Photoelectron%20and%20Absorption%20Spectroscopy%20Techniques.jpg?subformat=icon-180
|x icon-180
|y Restricted
856 4 _ |u https://juser.fz-juelich.de/record/844946/files/Charge%20Transfer%20Across%20Oxide%20Interfaces%20Probed%20by%20in%20Situ%20X-ray%20Photoelectron%20and%20Absorption%20Spectroscopy%20Techniques.jpg?subformat=icon-640
|x icon-640
|y Restricted
856 4 _ |u https://juser.fz-juelich.de/record/844946/files/Charge%20Transfer%20Across%20Oxide%20Interfaces%20Probed%20by%20in%20Situ%20X-ray%20Photoelectron%20and%20Absorption%20Spectroscopy%20Techniques.pdf?subformat=pdfa
|x pdfa
|y Restricted
909 C O |o oai:juser.fz-juelich.de:844946
|p VDB
910 1 _ |a Forschungszentrum Jülich
|0 I:(DE-588b)5008462-8
|k FZJ
|b 0
|6 P:(DE-Juel1)138081
913 1 _ |a DE-HGF
|l Speicher und vernetzte Infrastrukturen
|1 G:(DE-HGF)POF3-130
|0 G:(DE-HGF)POF3-135
|2 G:(DE-HGF)POF3-100
|v Fuel Cells
|x 0
|4 G:(DE-HGF)POF
|3 G:(DE-HGF)POF3
|b Energie
914 1 _ |y 2018
915 _ _ |a JCR
|0 StatID:(DE-HGF)0100
|2 StatID
|b J PHYS CHEM C : 2015
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0200
|2 StatID
|b SCOPUS
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0300
|2 StatID
|b Medline
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0199
|2 StatID
|b Thomson Reuters Master Journal List
915 _ _ |a WoS
|0 StatID:(DE-HGF)0110
|2 StatID
|b Science Citation Index
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0150
|2 StatID
|b Web of Science Core Collection
915 _ _ |a WoS
|0 StatID:(DE-HGF)0111
|2 StatID
|b Science Citation Index Expanded
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)1150
|2 StatID
|b Current Contents - Physical, Chemical and Earth Sciences
915 _ _ |a IF < 5
|0 StatID:(DE-HGF)9900
|2 StatID
920 _ _ |l yes
920 1 _ |0 I:(DE-Juel1)IEK-1-20101013
|k IEK-1
|l Werkstoffsynthese und Herstellungsverfahren
|x 0
980 _ _ |a journal
980 _ _ |a VDB
980 _ _ |a I:(DE-Juel1)IEK-1-20101013
980 _ _ |a UNRESTRICTED
981 _ _ |a I:(DE-Juel1)IMD-2-20101013

LibraryCollectionCLSMajorCLSMinorLanguageAuthor
Marc 21