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@ARTICLE{Sun:845295,
      author       = {Sun, Xueliang and Zhao, Yang and Yang, Xiaofei and Kuo,
                      Liang-Yin and Kaghazchi, Payam and Sun, Qian and Liang,
                      Jianneng and Wang, Biqiong and Lushington, Andrew and Li,
                      Ruying and Zhang, Huamin},
      title        = {{H}igh {C}apacity, {D}endrite-{F}ree {G}rowth, and
                      {M}inimum {V}olume {C}hange {N}a {M}etal {A}node},
      journal      = {Small},
      volume       = {14},
      number       = {20},
      issn         = {1613-6810},
      address      = {Weinheim},
      publisher    = {Wiley-VCH},
      reportid     = {FZJ-2018-02573},
      pages        = {1703717},
      year         = {2018},
      abstract     = {Na metal anode attracts increasing attention as a promising
                      candidate for Na metal batteries (NMBs) due to the high
                      specific capacity and low poten-tial. However, similar to
                      issues faced with the use of Li metal anode, crucial
                      problems for metallic Na anode remain, including serious
                      moss-like and den-dritic Na growth, unstable solid
                      electrolyte interphase formation, and large infinite volume
                      changes. Here, the rational design of carbon paper (CP) with
                      N-doped carbon nanotubes (NCNTs) as a 3D host to obtain
                      Na@CP-NCNTs composites electrodes for NMBs is demonstrated.
                      In this design, 3D carbon paper plays a role as a skeleton
                      for Na metal anode while vertical N-doped carbon nanotubes
                      can effectively decrease the contact angle between CP and
                      liquid metal Na, which is termed as being “Na-philic.”
                      In addition, the cross-conductive network characteristic of
                      CP and NCNTs can decrease the effective local current
                      density, resulting in uniform Na nucleation. Therefore, the
                      as-prepared Na@CP-NCNT exhibits stable electrochemical
                      plating/strip-ping performance in symmetrical cells even
                      when using a high capacity of 3 mAh cm−2 at high current
                      density. Furthermore, the 3D skeleton structure is observed
                      to be intact following electrochemical cycling with minimum
                      volume change and is dendrite-free in nature.},
      cin          = {IEK-1},
      ddc          = {540},
      cid          = {I:(DE-Juel1)IEK-1-20101013},
      pnm          = {899 - ohne Topic (POF3-899)},
      pid          = {G:(DE-HGF)POF3-899},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:29658174},
      UT           = {WOS:000434172700005},
      doi          = {10.1002/smll.201703717},
      url          = {https://juser.fz-juelich.de/record/845295},
}