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@ARTICLE{Wilden:845391,
      author       = {Wilden, Andreas and Mincher, Bruce J. and Mezyk, Stephen P.
                      and Twight, Liam and Rosciolo-Johnson, Kristyn M. and
                      Zarzana, Chris A. and Case, Mary E. and Hupert, Michelle and
                      Stärk, Andrea and Modolo, Giuseppe},
      title        = {{R}adiolytic and {H}ydrolytic {D}egradation of the
                      {H}ydrophilic {D}iglycolamides},
      journal      = {Solvent extraction and ion exchange},
      volume       = {36},
      number       = {4},
      issn         = {0736-6299},
      address      = {Philadelphia, PA},
      publisher    = {Taylor $\&$ Francis},
      reportid     = {FZJ-2018-02662},
      pages        = {347-359},
      year         = {2018},
      abstract     = {The stability of different hydrophilic diglycolamides
                      against acid degradation and radiolysis was studied.
                      Tetraethyldiglycolamide (TEDGA) was found to undergo
                      degradation in nitric acid at high reaction rates at
                      elevated temperatures with a maximum of a $~8\%$ decrease
                      per hour at 65°C in 4 mol L 1 HNO3. The radiolysis was
                      studied for tetramethyldiglycolamide (TMDGA), TEDGA,
                      methyl-tetraethyldiglycolamide (Me-TEDGA), and
                      dimethyl-tetraethyldiglycolamide (Me2-TEDGA). The
                      degradation rates decreased with increasing molecular
                      weight, following the trend TMDGA > TEDGA > Me-TEDGA ≥
                      Me2-TEDGA. Degradation products were identified by mass
                      spectrometric techniques and were found to be comparable to
                      those previously reported for the radiolysis of lipophilic
                      diglycolamides in dodecane. Significant insight into the
                      degradation mechanism in water was gained using pulse
                      radiolysis experiments. The •OH radical was identified as
                      the most important reactive species and predominant
                      mechanism of radical reaction is one of electron transfer
                      rather than H-atom abstraction.},
      cin          = {IEK-6 / ZEA-3},
      ddc          = {540},
      cid          = {I:(DE-Juel1)IEK-6-20101013 / I:(DE-Juel1)ZEA-3-20090406},
      pnm          = {161 - Nuclear Waste Management (POF3-161) / GENIORS - GEN
                      IV Integrated Oxide fuels recycling strategies (755171)},
      pid          = {G:(DE-HGF)POF3-161 / G:(EU-Grant)755171},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000445878000002},
      doi          = {10.1080/07366299.2018.1495384},
      url          = {https://juser.fz-juelich.de/record/845391},
}