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@ARTICLE{Khodan:845525,
author = {Khodan, A. N. and Kopitsa, G. P. and Yorov, Kh. E. and
Baranchikov, A. E. and Ivanov, V. K. and Feoktystov, Artem
and Pipich, Vitaliy},
title = {{S}tructural {A}nalysis of {A}luminum {O}xyhydroxide
{A}erogel by {S}mall {A}ngle {X}-{R}ay {S}cattering},
journal = {Journal of surface investigation},
volume = {12},
number = {2},
issn = {1819-7094},
address = {Moscow},
publisher = {MAIK Nauka/Interperiodics Publ.},
reportid = {FZJ-2018-02759},
pages = {296 - 305},
year = {2018},
abstract = {The work presents studies on the microstructure and
mesostructure of nanostructured aluminum oxyhydroxide formed
as a high porous monolithic material through the surface
oxidation of aluminum liquidmetal solution in mercury in a
temperature- and humidity-controlled air atmosphere. The
methods of X-ray diffraction analysis, thermal analysis, the
low temperature adsorption of nitrogen vapors, transmission
electron microscopy, small-angle and very small-angle
neutron scattering, and small-angle X-ray scattering are
used for comprehensive investigation of the samples
synthesized at 25°С as well as that annealed at
temperatures up to 1150°C. It is found that the structure
of the monolithic samples can be described within the
framework of a three-level model involving primary
heterogeneities (typical length scale of rc ≈ 9–19 Å),
forming fibrils (cross-sectional radius R ≈ 36–43 Å and
length L ≈ 3200–3300 Å) or lamellae (thickness T ≈
110 Å and width W ≈ 3050 Å) which, in turn, are
integrated into large-scale aggregates (typical size R c ≈
1.25–1.4 μm) with an insignificant surface roughness. It
is shown that a high specific surface (~200 m2/g) typical
for the initial sample is maintained upon its thermal
annealing up to 900°С, and it decreases to 100 m2/g after
heat treatment at 1150°С due to fibrillary agglomeration.},
cin = {JCNS (München) ; Jülich Centre for Neutron Science JCNS
(München) ; JCNS-FRM-II / Neutronenstreuung ; JCNS-1},
ddc = {530},
cid = {I:(DE-Juel1)JCNS-FRM-II-20110218 /
I:(DE-Juel1)JCNS-1-20110106},
pnm = {6G15 - FRM II / MLZ (POF3-6G15) / 6G4 - Jülich Centre for
Neutron Research (JCNS) (POF3-623)},
pid = {G:(DE-HGF)POF3-6G15 / G:(DE-HGF)POF3-6G4},
experiment = {EXP:(DE-MLZ)KWS2-20140101 / EXP:(DE-MLZ)KWS3-20140101},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000430991000017},
doi = {10.1134/S102745101802026X},
url = {https://juser.fz-juelich.de/record/845525},
}