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@ARTICLE{Pfrang:845932,
author = {Pfrang, A. and Kersys, A. and Kriston, A. and Sauer, Dirk
Uwe and Rahe, Christiane and Käbitz, Stefan and Figgemeier,
Egbert},
title = {{L}ong-term cycling induced jelly roll deformation in
commercial 18650 cells},
journal = {Journal of power sources},
volume = {392},
issn = {0378-7753},
address = {New York, NY [u.a.]},
publisher = {Elsevier},
reportid = {FZJ-2018-03130},
pages = {168-175},
year = {2018},
abstract = {The effects of extended charge/discharge cycling on the
morphology of the jelly roll of commercial 18650 lithium-ion
battery cells (Sanyo UR18650E) are shown and discussed.
Using micro X-ray computed tomography combined with
post-mortem analysis it is shown that the jelly roll
exhibits significant deformations after charge/discharge
cycling. This effect appears despite the presence of a solid
inner pin, which had been suggested in literature as
prohibitive for jelly roll deformation. The effect is
related to an inhomogeneous architecture of the cells caused
mainly by the cathode tab in the vicinity of which
deformations were observed most often. While it is shown
here that such deformations eventually lead to delamination
of the otherwise rather stable cathode coating and cause a
rapid capacity fade, jelly roll deformation has also been
observed after more than 1700 equivalent full cycles on
cells which show a typical, non-accelerated ageing behavior
for this cell type. A correlation between occurrence of
delamination and occurrence of deformation was clearly
identified by combining post-mortem and computed tomography
analysis. It is discussed, if the well-documented
deformation is caused by thickness variations of the anode
and cathode during charge/discharge cycles. Furthermore, an
in-depth characterization of the cell design is documented.},
cin = {IEK-12},
ddc = {620},
cid = {I:(DE-Juel1)IEK-12-20141217},
pnm = {131 - Electrochemical Storage (POF3-131)},
pid = {G:(DE-HGF)POF3-131},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000435055500019},
doi = {10.1016/j.jpowsour.2018.03.065},
url = {https://juser.fz-juelich.de/record/845932},
}