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@ARTICLE{Volz:847991,
author = {Volz, N. and Zenk, C. H. and Cherukuri, R. and Kalfhaus, T.
and Weiser, M. and Makineni, S. K. and Betzing, C. and Lenz,
M. and Gault, B. and Fries, S. G. and Schreuer, J. and
Vaßen, R. and Virtanen, S. and Raabe, D. and Spiecker, E.
and Neumeier, S. and Göken, M.},
title = {{T}hermophysical and {M}echanical {P}roperties of
{A}dvanced {S}ingle {C}rystalline {C}o-base {S}uperalloys},
journal = {Metallurgical and materials transactions / A},
volume = {49A},
number = {9},
issn = {1543-1940},
address = {Boston},
publisher = {Springer},
reportid = {FZJ-2018-03299},
pages = {4099-4109},
year = {2018},
abstract = {A set of advanced single crystalline γ′ strengthened
Co-base superalloys with at least nine alloying elements
(Co, Ni, Al, W, Ti, Ta, Cr, Si, Hf, Re) has been developed
and investigated. The objective was to generate multinary
Co-base superalloys with significantly improved properties
compared to the original Co-Al-W-based alloys. All alloys
show the typical γ/γ′ two-phase microstructure. A γ′
solvus temperature up to 1174 °C and γ′ volume fractions
between 40 and 60 pct at 1050 °C could be achieved, which
is significantly higher compared to most other Co-Al-W-based
superalloys. However, higher contents of Ti, Ta, and the
addition of Re decrease the long-term stability. Atom probe
tomography revealed that Re does not partition to the γ
phase as strongly as in Ni-base superalloys. Compression
creep properties were investigated at 1050 °C and 125 MPa
in 〈001〉 direction. The creep resistance is close to
that of first generation Ni-base superalloys. The creep
mechanisms of the Re-containing alloy was further
investigated and it was found that the deformation is
located preferentially in the γ channels although some
precipitates are sheared during early stages of creep. The
addition of Re did not improve the mechanical properties and
is therefore not considered as a crucial element in the
design of future Co-base superalloys for high temperature
applications. Thermodynamic calculations describe well how
the alloying elements influence the transformation
temperatures although there is still an offset in the actual
values. Furthermore, a full set of elastic constants of one
of the multinary alloys is presented, showing increased
elastic stiffness leading to a higher Young’s modulus for
the investigated alloy, compared to conventional Ni-base
superalloys. The oxidation resistance is significantly
improved compared to the ternary Co-Al-W compound. A
complete thermal barrier coating system was applied
successfully},
cin = {IEK-1},
ddc = {670},
cid = {I:(DE-Juel1)IEK-1-20101013},
pnm = {113 - Methods and Concepts for Material Development
(POF3-113)},
pid = {G:(DE-HGF)POF3-113},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000440714700028},
doi = {10.1007/s11661-018-4705-1},
url = {https://juser.fz-juelich.de/record/847991},
}