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@ARTICLE{Wang:848260,
author = {Wang, An-Ni and Nonemacher, Juliane Franciele and Yan, Gang
and Finsterbusch, Martin and Malzbender, Jürgen and
Krüger, Manja},
title = {{M}echanical properties of the solid electrolyte
{A}l-substituted {L}i 7 {L}a 3 {Z}r 2 {O} 12 ({LLZO}) by
utilizing micro-pillar indentation splitting test},
journal = {Journal of the European Ceramic Society},
volume = {38},
number = {9},
issn = {0955-2219},
address = {Amsterdam [u.a.]},
publisher = {Elsevier Science},
reportid = {FZJ-2018-03522},
pages = {3201 - 3209},
year = {2018},
abstract = {Garnet structured Al-substituted Li7La3Zr2O12 (Al:LLZO) is
a promising candidate as electrolyte in all-solid-state
Li-ion batteries due to its chemical stability against
Li-metal and high voltage cathode materials. In order to
ensure long-term stable operation, electrolyte crack growth
induced and/or the volume change of the active material on
the cathode side needs to be avoided, requiring in
particular knowledge of local and global mechanical
properties of the electrolyte material. Micro-pillar
splitting test was used for the first time on this material
to determine the microscopic fracture toughness of single
grains and compare it with conventional Vickers indentation
fracture toughness (VIF), which represents macroscopic
fracture toughness. Both methods yielded comparative
results. In conclusion, the micro-pillar splitting test can
be used as an advanced locally resolved characterization
method that can open up new experimental directions for
characterizing and understanding battery materials and
enable a targeted approach for material improvements.},
cin = {IEK-1 / IEK-2},
ddc = {660},
cid = {I:(DE-Juel1)IEK-1-20101013 / I:(DE-Juel1)IEK-2-20101013},
pnm = {111 - Efficient and Flexible Power Plants (POF3-111)},
pid = {G:(DE-HGF)POF3-111},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000433014200019},
doi = {10.1016/j.jeurceramsoc.2018.02.032},
url = {https://juser.fz-juelich.de/record/848260},
}