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000848332 0247_ $$2doi$$a10.1016/j.jpowsour.2018.06.035
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000848332 1001_ $$0P:(DE-Juel1)173718$$aLi, Dongjiang$$b0$$ufzj
000848332 245__ $$aTemperature-dependent cycling performance and ageing mechanisms of C 6 /LiNi 1/3 Mn 1/3 Co 1/3 O 2 batteries
000848332 260__ $$aNew York, NY [u.a.]$$bElsevier$$c2018
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000848332 520__ $$aAgeing mechanisms of NMC-based Li-ion (C6/LiNi1/3Mn1/3Co1/3O2) batteries have been investigated under various cycling conditions. The electromotive force (EMF) curves are regularly determined by mathematical extrapolation of voltage discharge curves. The irreversible capacity losses determined from the EMF curves have been investigated as a function of time and cycle number. Parasitic side reactions, occurring at the cathode and anode, determine the charge-discharge efficiency (CDE) and discharge-charge efficiency (DCE), respectively. The recently developed non-destructive voltage analysis method is also applied to the present battery chemistry. The decline of the second plateau of the dVEMF/dQdVEMF/dQ curves upon cycling is considered to be an indicator of graphite degradation whereas the development of the third peak in these derivative curves is considered to be an indicator for electrode voltage slippage. X-ray Photoelectron Spectroscopy (XPS) measurements confirm the deposition of transition-metal elements at the graphite electrode, indicating dissolution of these metals from the cathode. Furthermore, XPS analyses confirm the existence of a Cathode-Electrolyte-Interface (CEI) layer. The outer CEI layer is composed of various compounds, such as carbonate-related Li salts, LiF and NiF2, etc., while the inner CEI layer is dominantly composed of fluoride-related compounds, such as NiF2. Finally, a cathode degradation model including transition-metal dissolution and electrolyte decomposition is proposed
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000848332 7001_ $$0P:(DE-HGF)0$$aLi, Hu$$b1
000848332 7001_ $$0P:(DE-Juel1)173719$$aDanilov, Dmitri$$b2$$ufzj
000848332 7001_ $$0P:(DE-HGF)0$$aGao, Lu$$b3
000848332 7001_ $$0P:(DE-HGF)0$$aZhou, Jiang$$b4
000848332 7001_ $$0P:(DE-Juel1)156123$$aEichel, Rüdiger-A.$$b5$$ufzj
000848332 7001_ $$0P:(DE-HGF)0$$aYang, Yong$$b6$$eCorresponding author
000848332 7001_ $$0P:(DE-Juel1)165918$$aNotten, Peter H. L.$$b7$$eCorresponding author$$ufzj
000848332 773__ $$0PERI:(DE-600)1491915-1$$a10.1016/j.jpowsour.2018.06.035$$gVol. 396, p. 444 - 452$$p444 - 452$$tJournal of power sources$$v396$$x0378-7753$$y2018
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000848332 9101_ $$0I:(DE-HGF)0$$6P:(DE-Juel1)173718$$a State Key Lab for Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, China$$b0
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000848332 9101_ $$0I:(DE-HGF)0$$6P:(DE-HGF)0$$a University of Eindhoven$$b3
000848332 9101_ $$0I:(DE-HGF)0$$6P:(DE-HGF)0$$a Tianjin Lishen Battery Joint-stock Co., Ltd, Tianjin, 300384, China$$b4
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000848332 9101_ $$0I:(DE-HGF)0$$6P:(DE-Juel1)165918$$a University of Eindhoven$$b7
000848332 9101_ $$0I:(DE-HGF)0$$6P:(DE-Juel1)165918$$aUniversity of Technology Sydney, Broadway, Sydney, NSW, 2007, Australia$$b7
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