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@ARTICLE{Li:848332,
      author       = {Li, Dongjiang and Li, Hu and Danilov, Dmitri and Gao, Lu
                      and Zhou, Jiang and Eichel, Rüdiger-A. and Yang, Yong and
                      Notten, Peter H. L.},
      title        = {{T}emperature-dependent cycling performance and ageing
                      mechanisms of {C} 6 /{L}i{N}i 1/3 {M}n 1/3 {C}o 1/3 {O} 2
                      batteries},
      journal      = {Journal of power sources},
      volume       = {396},
      issn         = {0378-7753},
      address      = {New York, NY [u.a.]},
      publisher    = {Elsevier},
      reportid     = {FZJ-2018-03576},
      pages        = {444 - 452},
      year         = {2018},
      abstract     = {Ageing mechanisms of NMC-based Li-ion
                      (C6/LiNi1/3Mn1/3Co1/3O2) batteries have been investigated
                      under various cycling conditions. The electromotive force
                      (EMF) curves are regularly determined by mathematical
                      extrapolation of voltage discharge curves. The irreversible
                      capacity losses determined from the EMF curves have been
                      investigated as a function of time and cycle number.
                      Parasitic side reactions, occurring at the cathode and
                      anode, determine the charge-discharge efficiency (CDE) and
                      discharge-charge efficiency (DCE), respectively. The
                      recently developed non-destructive voltage analysis method
                      is also applied to the present battery chemistry. The
                      decline of the second plateau of the dVEMF/dQdVEMF/dQ curves
                      upon cycling is considered to be an indicator of graphite
                      degradation whereas the development of the third peak in
                      these derivative curves is considered to be an indicator for
                      electrode voltage slippage. X-ray Photoelectron Spectroscopy
                      (XPS) measurements confirm the deposition of
                      transition-metal elements at the graphite electrode,
                      indicating dissolution of these metals from the cathode.
                      Furthermore, XPS analyses confirm the existence of a
                      Cathode-Electrolyte-Interface (CEI) layer. The outer CEI
                      layer is composed of various compounds, such as
                      carbonate-related Li salts, LiF and NiF2, etc., while the
                      inner CEI layer is dominantly composed of fluoride-related
                      compounds, such as NiF2. Finally, a cathode degradation
                      model including transition-metal dissolution and electrolyte
                      decomposition is proposed},
      cin          = {IEK-9},
      ddc          = {620},
      cid          = {I:(DE-Juel1)IEK-9-20110218},
      pnm          = {131 - Electrochemical Storage (POF3-131)},
      pid          = {G:(DE-HGF)POF3-131},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000440876700052},
      doi          = {10.1016/j.jpowsour.2018.06.035},
      url          = {https://juser.fz-juelich.de/record/848332},
}