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@TECHREPORT{Eckold:849717,
author = {Eckold, G.},
title = {{UNISOFT}: a program package for lattice dynamical
calculations: user manual},
volume = {2639},
number = {Juel-2639},
address = {Jülich},
publisher = {Forschungszentrum Jülich GmbH Zentralbibliothek, Verlag},
reportid = {FZJ-2018-03850, Juel-2639},
series = {Berichte des Forschungszentrums Jülich},
pages = {X, 117 p.},
year = {1992},
abstract = {Lattice-dynamical investigations provide a powerful tool
for the determination of interatomic forces and chemical
bonding in crystals. In general the extraction of,
say,potential parameters from phonon dispersion curves, as
determined experimentally, is possible with the help of
model calculations only. Phonons which are cooperative
excitations in many-body systems provide informations about
interactions within the whole crystal. A quantitative
interpretation of single phonons is therefore restricted to
very simple crystal structures. In general, however,
unambigious statements about interatomic forces require the
knowledge of a good number of the phonon branches, at least
in the symmetry directions. Often, the determination of
phonon dispersion curves is a rather hard task since a
crystal with N particles per unit cell exhibits as many as
3N phonon branches. The only experimental method which
allows the detection of phonons at arbitrary points within
the Brillouin zone is the inelastic neutron scattering.
Again, model calculations are very useful and sometimes even
necessary in order to find phonons experimentally since
phonon intensities vary strongly from one Brillouin zone to
another and are determined by the corresponding
eigenvectors. For complex structures, model calculations and
neutron scattering experiments are thus complementary. The
determination of interatomic forces in crystals requires
both, the theoretical and the experimental approach which
need to go hand in hand. The three-axes spectrometer UNIDAS
at the FRJ-2 reactor at Jülich is available to external
users and is especially designed to meet the requirements
for phonon investigations. Details of this machine are
described in the UNIDAS-Handbuch [1]. In the present paper
we report an the complement to this spectrometer, namely the
computer program package UNISOFT which allows to perform
model calculations an phonon dispersion in general
structures with up to 20 particles per primitive cell.
UNISOFT has been developed in order to provide a tool for
the optimization of experiments as well as for a first
interpretation of the results. Certainly, a general
lattice-dynamical program cannot deal with the most complex
models for interatomic interactions. Until now the standard
models such as $\bullet$ Born-von Kärmän model
(longitudinal and transverse springs) $\bullet$ Born-Mayer
potential $\bullet$ Lennard-Jones potentialvan der Waals
potential $\bullet$ Coulomb potential (Ewald's method of
summation) $\bullet$ shell model are implemented. The
interaction between each pair of atoms can be chosen
individually as an arbitrary combination of these model
potentials. More sophisticated models must be developed by
the user and are beyond the scope of UNISOFT as a
universally applicable lattice-dynamical program. Special
attention has been paid to the handling of this program
package by external users. Offering the possibility of a
tailored interatomic interaction set-up for each individual
substance under consideration, the system is rather complex,
of course.Universality of the programs, however, does not
exclude an easy mode of operation. Thus, UNISOFT can indeed
be used in combination with UNIDAS by experimenters which
are not familiar with details of lattice-dynamical
calculations and the interpretation of phonon dispersion
curves. This combination of software and hardware is able to
simplify the determination of interatomic forces in crystals
even for nonspecialists. Chapter 2 of this report briefly
reviews the theoretical background of lattice dynamics in
the harmonic approximation along with group-theoretical
considerations and symmetry constraints to the dynamical
matrix. The response of a phonon system in neutron
scattering experiments is also discussed. In section 3 the
global structure of the program package is displayed before
a detailed description of the individual programs is given
in chapter 4. Section 5 deals with computer requirements.
Some possible extensions of this program system are
discussed in chapter 6. In order to illustrate all
information available with UNISOFT, an example for a
complete treatment of a crystal structure within this
program system is presented in appendix A. Finally, a
comprehensive list of all input cards, the alphabetical list
of subroutines, the subroutine reference list and the list
of symbols used in this manual are given in the appendices
B, C, D and E. Concerning the notation, matrices are denoted
by bold printed capital letters and vectors are represented
by bold printed lower case letters.},
cin = {PRE-2000},
cid = {I:(DE-Juel1)PRE2000-20140101},
pnm = {899 - ohne Topic (POF3-899)},
pid = {G:(DE-HGF)POF3-899},
typ = {PUB:(DE-HGF)3 / PUB:(DE-HGF)29},
url = {https://juser.fz-juelich.de/record/849717},
}