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000849726 245__ $$aCrystal structure and magnetism of the Fe x Ni 8-x Si 3 materials, 0 ≤ x ≤ 8
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000849726 520__ $$aThe crystal structure and magnetic properties of the materials FexNi8-xSi3 with 0 ≤ x ≤ 8 have been investigated to estimate any possible magnetocaloric effect and compare it to that in known magnetocalorics. Two structural ranges could be identified in this system by X-ray and neutron diffraction. The structure of the samples with 0 ≤ x ≤ 4 is related to the trigonal structure of Ni31Si12. Doubled c lattice parameters compared to the one in Ni31Si12 are observed in the samples with x = 2 and x = 3. The average structure of Fe2Ni6Si3 has been determined by X-ray single-crystal diffraction. The compounds with the compositions 5 ≤ x ≤ 8 crystallize in cubic Fe3Si-type structure. Magnetic measurements have shown that the compound Fe3Ni5Si3 displays a phase transition close to room temperature. However, its magnetocaloric effect is much smaller than the one in the promising magnetocaloric materials.
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000849726 7001_ $$0P:(DE-Juel1)172834$$aAit Haddouch, Mohammed$$b1
000849726 7001_ $$00000-0002-1698-9007$$aChikovani, Mamuka$$b2
000849726 7001_ $$0P:(DE-Juel1)130884$$aPersson, Jörg$$b3
000849726 7001_ $$0P:(DE-Juel1)131018$$aVoigt, Jörg$$b4
000849726 7001_ $$0P:(DE-Juel1)145694$$aFriese, Karen$$b5
000849726 7001_ $$0P:(DE-HGF)0$$aSenyshyn, Anatoliy$$b6
000849726 7001_ $$0P:(DE-HGF)0$$aGrzechnik, Andrzej$$b7$$eCorresponding author
000849726 773__ $$0PERI:(DE-600)2035101-X$$a10.1016/j.solidstatesciences.2017.12.005$$gVol. 76, p. 57 - 64$$p57 - 64$$tSolid state sciences$$v76$$x1293-2558$$y2018
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